Synthesis of asymmetric biphenyl derivatives for optoelectronicapplications

Cai-Cai Zhu; Kun-Ping Guo; Wang-Bo Liu; Yan-Bo He; Zhi-Mei Li; Xi-Cun Gao; Feng-Jie Deng; Bin Wei

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Synthesis of asymmetric biphenyl derivatives for optoelectronicapplications

机译：光电应用中不对称联苯衍生物的合成

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We report the synthesis and optical properties of a series often organic compounds with biphenyl as the backbone and asymmetrically modified by triphenylamines, carbazoles and tetraphenylsilanes (BP1-10). BP1-10 were synthesized mainly by Ullmann coupling reaction and Suzuki cross-coupling reaction and characterized by EA, NMR, MS, UV-Vis, DSC, TGA, fluorescence spectra and cyclic voltammetry. They exhibit reversible electrochemical behavior with low oxidation potentials and emit intense pure-blue light with high fluorescence quantum yields (up to 80%). BP 1 was fabricated into multi-layered light-emitting diodes as blue-emitting, host and hole transport materials. Based on the performance of BP 1 and the similarity in chemical structure to those compounds reported in literature, these compounds are expected to be good and versatile hole transport, host and blue emitting materials.

机译：我们报告了一系列以联苯为骨架并被三苯胺，咔唑和四苯硅烷（BP1-10）不对称改性的经常有机化合物的合成和光学性质。 BP1-10主要通过Ullmann偶联反应和Suzuki交叉偶联反应合成，并通过EA，NMR，MS，UV-Vis，DSC，TGA，荧光光谱和循环伏安法表征。它们表现出可逆的电化学行为，具有低氧化电位，并发出具有高荧光量子产率（高达80％）的强纯蓝光。 BP 1被制成多层发光二极管，作为发蓝光，主体和空穴传输的材料。基于BP 1的性能以及与文献中报道的那些化合物在化学结构上的相似性，这些化合物有望成为良好且用途广泛的空穴传输，基质和发蓝光材料。

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来源
《Optical Materials》 |2013年第12期|2095-2101|共7页
作者
Cai-Cai Zhu; Kun-Ping Guo; Wang-Bo Liu; Yan-Bo He; Zhi-Mei Li; Xi-Cun Gao; Feng-Jie Deng; Bin Wei;
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作者单位

Department of Chemistry School of Science Nanchang University Xue-Fu Road 999 Hong-Gu-Tan New District Nanchang 330031 China;

Key Laboratory of Advanced Display and System Applications Ministry of Education Shanghai University Shanghai 200072 China;

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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);
原文格式 PDF
正文语种 eng
中图分类
关键词
Biphenyl derivatives; Triphenylamine; Carbazole; Tetraphenylsilane; Ullmann coupling; Suzuki coupling;

机译：联苯衍生物;三苯胺;咔唑四苯基硅烷;乌尔曼联轴器;铃木联轴器;

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2. Enantiodivergent Synthesis of Axially Chiral Biphenyls from sigma-Symmetric 1,1'-Biphenyl-2,6-diol Derivatives by Single Lipase-Catalyzed Acylative and Hydrolytic Desymmetrization [J] . Kasama Kengo, Aoyama Hiroshi, Akai Shuji European journal of organic chemistry . 2020,第6期

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机译：二取代联苯衍生物：联苯-4,40-二乙酸的合成，结构，光谱及热性质
4. Synthesis and Characterization of copolymers consisting of 3-hexylthiophene and biphenyl derivatives [C] . Fude Liu, Yong Zhou, Haiyan Wu 2013 International conference on process equipment, mechatronics engineering and material science . 2013

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6. Asymmetric Catalysis Special Feature Part II: Remarkably diastereoselective synthesis of a chiral biphenyl diphosphine ligand and its application in asymmetric hydrogenation [O] . Liqin Qiu, Jing Wu, Shusun Chan, 2004

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Synthesis of asymmetric biphenyl derivatives for optoelectronicapplications

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