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High pressure luminescence and time resolved spectra of La_2Be_2O_5:Pr~(3+)

机译:La_2Be_2O_5:Pr〜(3+)的高压发光和时间分辨光谱

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摘要

We present luminescence, luminescence excitation and luminescence time resolved spectra of La_2Be_2O_5:Pr~(3+) system. We used high pressure spectroscopy approaches, with high pressure applied in diamond anvil cell (DAC) and sapphire anvil cell (SAC), for detailed analysis of luminescence related to the 4f5d →4F_2 and 4F_2→4F_2 transitions. We present effect of up-converted luminescence related to 4f5d→4F_2 transition excited with 488 nm. We also discussed possibility of existence of praseodymium trapped exciton (PTE) states in La_2Be_2O_5:Pr~(3+) system. Lack of the PTE is attributed to high quantity of bulk modulus of this material.
机译:给出了La_2Be_2O_5:Pr〜(3+)体系的发光,发光激发和发光时间分辨光谱。我们使用高压光谱方法,对金刚石砧盒(DAC)和蓝宝石砧盒(SAC)施加高压,以详细分析与4f5d→4F_2和4F_2→4F_2跃迁相关的发光。我们提出与488 nm激发的4f5d→4F_2跃迁有关的上转换发光的影响。我们还讨论了La_2Be_2O_5:Pr〜(3+)系统中存在trap捕获激子(PTE)状态的可能性。 PTE的缺乏归因于这种材料的高体积模量。

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