Synthesis of polyfluorene derivatives through polymer reaction

Bin Liu; Wang-Lin Yu; Yee-Hing Lai; Wei Huang

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Synthesis of polyfluorene derivatives through polymer reaction

机译：高分子反应合成聚芴衍生物

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A polyfluorene derivative with ester functional groups was synthesized with a high molecular weight and good solubility in common organic solvents through the Suzuki reaction. Efficient blue light emission and good electrochemical properties were demonstrated for this polymer with a decomposition temperature of 331℃ and a glass transition temperature of 111 ℃. Due to the ester functional groups, the polymer could be further modified through polymer reactions. Hydrolysis of the polymer afforded a water-soluble carbonate functional polyfluorene derivative. While it underwent a reduction, a new polyfluorene derivative with hydroxy functional groups was obtained. Thermal and optical properties of the derivatives were also studied.

机译：通过Suzuki反应合成了具有酯官能团的聚芴衍生物，该衍生物具有高分子量和在普通有机溶剂中的良好溶解性。该聚合物具有331℃的分解温度和111℃的玻璃化转变温度，具有高效的蓝光发射性能和良好的电化学性能。由于酯官能团，可以通过聚合物反应进一步改性聚合物。聚合物的水解得到水溶性碳酸酯官能的聚芴衍生物。在进行还原的同时，获得了具有羟基官能团的新的聚芴衍生物。还研究了衍生物的热和光学性质。

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来源
《Optical Materials》 |2003年第3期|p.125-133|共9页
作者
Bin Liu; Wang-Lin Yu; Yee-Hing Lai; Wei Huang;
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作者单位

Institute of Materials Research and Engineering (IMRE) National University of Singapore 3 Research Link Singapore 117602 Singapore;

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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);
原文格式 PDF
正文语种 eng
中图分类工程材料学;
关键词
polyfluorene; water-soluble; polymer reaction;

机译：聚芴水溶性;聚合物反应;

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1. Parallel Polymer Reactions of a Polyfluorene Derivative by Electrochemical Oxidation and Reduction [J] . Shinsuke Inagi, Hiroyuki Nagai, Ikuyoshi Tomita Angewandte Chemie . 2013,第26期

机译：聚芴衍生物的电化学氧化和还原反应的平行聚合物反应
2. Synthesis and characterization of new polyfluorene derivatives: using phenanthro[9,10-d]imidazole group as a building block for deep blue light-emitting polymer [J] . Zhiming Wang, Zhao Gao, Shanfeng Xue Polymer bulletin . 2012,第3期

机译：新型聚芴衍生物的合成与表征：使用菲咯啉[9,10-d]咪唑基作为深蓝色发光聚合物的结构单元
3. Synthesis and characterization of new polyfluorene derivatives: using phenanthro[9,10-d]imidazole group as a building block for deep blue light-emitting polymer [J] . Zhiming Wang, Zhao Gao, Shanfeng Xue, Polymer Bulletin . 2012,第3期

机译：新型聚芴衍生物的合成与表征：使用菲咯啉[9,10-d]咪唑基作为深蓝色发光聚合物的结构单元
4. Preparation and Characterization of Novel Polyfluorenes Derivatives Containing Phenanthro9, 10-dimidazole Group for Deep Blue-Light-Emitting Polymers [C] . Zhiming Wang, Lingling Ma, Xiaojuan Zhang International Conference on Advanced Technologies and Solutions in Industry . 2013

机译：深蓝发光聚合物的菲尼9,10-D咪唑基的新型多氟胺衍生物的制备与表征
5. Synthesis, reactions, and applications of bis-ortho-diynyl arene (BODA) monomers, polymers, and derivatives. [D] . Perpall, Mark Wilson. 2007

机译：双邻二炔基芳烃（BODA）单体，聚合物和衍生物的合成，反应和应用。
6. Synthesis and reactions of a nucleoside derivative of phosphoric sulfonic anhydride. Studies related to the mechanisms of coupling reactions in the chemical synthesis of oligodeoxyribonucleotides by phosphotriester procedures. [O] . W Dabkowski, Z Skrzypczynski, J Michalski, 1984

机译：磷磺酸酐的核苷衍生物的合成和反应。有关通过磷酸三酯方法化学合成寡脱氧核糖核苷酸中偶联反应机理的研究。
7. Chain-Growth Polymerization for the Synthesis of Polyfluorene via Suzuki-Miyaura Coupling Reaction from an Externally Added Initiator Unit [O] . -1

机译：链生长聚合用于通过来自外部添加的引发单元通过Suzuki-miyaura偶联反应合成多氟烯的聚合
8. Phase Transfer Pd(O) Catalyzed Polymerization Reactions. 1. Synthesis of 1,2-(4,4'-Dialkoxyaryl)Acetylene Monomers and 1,4-Bis(2-(4',4''-Dialkoxyphenyl)Ethynyl)Benzene Derivatives by Phase Transfer Pd(O)/Cu(I) Catalyzed Coupling Reactions. [R] . Pugh, C., Percec, V. 1990

机译：相转移pd（O）催化的聚合反应。 1.相转移pd（O）/ Cu合成1,2-（4,4'-二烷氧基芳基）乙炔单体和1,4-双（2-（4'，4'-二烷氧基苯基）乙炔基）苯衍生物（I）催化的偶联反应。

Synthesis of polyfluorene derivatives through polymer reaction

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