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Temperature hysteresis of the order-disorder transition in carbon-supersaturated a-Fe

机译:碳过饱和a-Fe中有序-无序转变的温度迟滞

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摘要

Although many works have been devoted to the order-disorder transition in carbon-supersaturated a-Fe, all seem to have overlooked the temperature hysteresis phenomenon occurring around the critical temperature. It is shown, from a mean-field model based on the elasticity theory of point defects, that the origin of the temperature hysteresis is thermodynamic. As a consequence, both the critical temperature and carbon concentration for the order-disorder transition can be defined upon heating and cooling. The results obtained were successfully compared to molecular dynamics simulations, and are evidence that the transition is of first order and that linear elasticity is the predominant source of the thermodynamics of the Fe-C solid solutions.
机译:尽管许多工作致力于碳过饱和a-Fe的有序-无序过渡,但似乎都忽略了临界温度附近发生的温度滞后现象。从基于点缺陷弹性理论的平均场模型可以看出,温度滞后的起因是热力学的。结果,可以在加热和冷却时确定用于有序-无序转变的临界温度和碳浓度。获得的结果已成功地与分子动力学模拟进行了比较,并证明了过渡是一级的,线性弹性是Fe-C固溶体热力学的主要来源。

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  • 来源
    《Physical review》 |2017年第21期|214104.1-214104.8|共8页
  • 作者单位

    Aix-Marseille Universite, Universite Toulon, CNRS, IM2NP, Marseille, France;

    Normandie Universite, UNIROUEN, INSA Rouen, CNRS, Groupe de Physique des Materiaux, Rouen, France;

    Normandie Universite, UNIROUEN, INSA Rouen, CNRS, Groupe de Physique des Materiaux, Rouen, France;

    Universite de Lyon, INSA Lyon, MATEIS-CNRS, Lyon, France;

    ICMCB-CNRS, Pessac, France;

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