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Mapping the surface electrostatic potentials of Au(111) by using barrier-height measurements

机译:通过势垒高度测量绘制Au(111)的表面静电势

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摘要

The surface electrostatic potential of Au(111) has been evaluated by using site-specific barrier-height measurements in a scanning tunneling microscope. From the spatial variation of the barrier height, sharp enlargement and reduction of the surface potential are obtained at the upper and lower step edges, respectively, which are characterized as the Smoluchowski effect. We also observe the potential with oscillatory decay away from the step, known as the Friedel potential oscillation. In addition, the periodic potential modulation induced by the surface reconstruction is evaluated quantitatively, which is confirmed by the energy shift of the bulk electronic states.
机译:Au(111)的表面静电势已通过在扫描隧道显微镜中使用特定位置的势垒高度测量进行了评估。从势垒高度的空间变化,分别在上和下阶梯边缘获得表面势的急剧增大和减小,这被表征为斯莫卢霍夫斯基效应。我们还观察到振荡衰减远离阶跃的电势,称为Friedel电势振荡。另外,定量地评估了由表面重构引起的周期性电势调制,这由体电子态的能量位移证实。

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