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Studies of the periodic faceting of epitaxial molybdenum oxide grown on Mo(110)

机译:Mo(110)上生长的外延氧化钼周期性刻面的研究

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We show that an oxide film can undergo a periodic self-faceting regime during growth. The oxide growth starts as a bulklike MoO_2 surface oxide trilayer that wets the substrate in an orientation thermodynamically forbidden in the bulk. As this film continues to grow, it develops into a periodically faceted surface with nanowirelike structures composed of MoO_2 (0 2 1) and (0 2 -1) faces. Through the use of density functional theory, it is found that this faceted surface has a lower surface free energy than the initial growth orientation. Finally, using the theory of faceted surfaces, we demonstrate that the periodicity of the facets is likely an equilibrium state that is related to the elastic properties of the film.
机译:我们表明,氧化膜在生长过程中会经历周期性的自成膜状态。氧化物的生长始于块状的MoO_2表面氧化物三层,该层以热力学上禁止的方向润湿衬底。随着该膜的继续生长,它发展成具有由MoO_2(0 2 1)和(0 2 -1)面组成的纳米线状结构的周期性刻面表面。通过使用密度泛函理论,发现该多面表面的表面自由能低于初始生长方向。最后,使用刻面表面理论,我们证明了刻面的周期性很可能是与薄膜的弹性相关的平衡状态。

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