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Symmetry fingerprints of a benzene single-electron transistor: Interplay between Coulomb interaction and orbital symmetry

机译:苯单电子晶体管的对称指纹:库仑相互作用与轨道对称之间的相互作用

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摘要

The interplay between Coulomb interaction and orbital symmetry produces specific transport characteristics in molecular single electron transistors (SETs) that can be considered as the fingerprints of the contacted molecule. Specifically we predict, for a benzene SET, selective conductance suppression and the appearance of negative differential conductance when changing the contacts from para to meta configuration. Both effects originate from destructive interference in transport involving states with orbital degeneracy.
机译:库仑相互作用和轨道对称性之间的相互作用在分子单电子晶体管(SET)中产生特定的传输特性,可以认为这是接触分子的指纹。特别是,对于苯SET,我们预测将触点从对位配置更改为间位配置时,选择性电导抑制作用和负微分电导的出现。两种影响都源于对轨道退化状态的运输的破坏性干扰。

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