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X-ray study of the crystal structure of La_(1-x)Ba_xMnO_3

机译:La_(1-x)Ba_xMnO_3晶体结构的X射线研究

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The x-ray study of the crystal structure of La_(1-x)Ba_xMnO_3 (0.14≤x≤0.25) single crystal manganites has been performed at temperatures from 80 to 400 K. In all the crystals, the transition from the low-temperature orthorhombic Pnma phase to the high-temperature rhombohedral R3c phase has been observed. In the x =0.20 and 0.25 manganites, the Pnma and R3c phases coexist in the range of 20-30 K width while in the x =0.14 and 0.15 crystals, the mixture of the phases has been found in a range whose width exceeds 150 K. The Pnma-R3c transition heat and the change in the cell volume have been shown to be very small as compared to manganites.
机译:在80至400 K的温度下对La_(1-x)Ba_xMnO_3(0.14≤x≤0.25)单晶锰矿的晶体结构进行了x射线研究。在所有晶体中,都从低温转变已经观察到正交晶系Pnma相到高温菱形R3c相。在x = 0.20和0.25锰矿中,Pnma和R3c相共存于20-30 K宽度范围内,而在x = 0.14和0.15晶体中,发现相的混合物在宽度超过150 K的范围内与锰矿相比,Pnma-R3c的转变热和晶胞体积的变化已显示非常小。

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