Role of hydrogen interaction in two-dimensional molecular packing with strong molecule-substrate bonding

V. Langlais; X. Torrelles; Y. Gauthier; M. De Santis

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Role of hydrogen interaction in two-dimensional molecular packing with strong molecule-substrate bonding

机译：氢相互作用在具有牢固的分子-底物键合的二维分子堆积中的作用

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Calixarene molecules deposited on Au(110) self-organize giving rise to a (19 × 6) coincidence cell with the substrate. Using grazing incidence x-ray diffraction, the structure has been completely resolved: gold reconstructs with a (1 × 3) missing-row structure while the molecules form a (19/6 × 6) surface cell containing two molecules. This study opens perspectives to create long-range ordered molecular templates to be used as receptors for other species providing an example of collaborative self-arrangement through a metallic substrate acting as guide and molecular flexibility.

机译：沉积在Au（110）上的杯芳烃分子自组织，与底物形成一个（19×6）符合单元。使用掠入射x射线衍射，该结构已被完全解析：金以（1×3）缺失行结构重建，而分子形成一个包含两个分子的（19/6×6）表面单元。这项研究为创建长程有序分子模板以用作其他物种的受体打开了视野，并提供了通过金属底物充当指导和分子柔性的协同自我排列的实例。

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来源
《Physical review》 |2007年第3期|035433.1-035433.7|共7页
作者
V. Langlais; X. Torrelles; Y. Gauthier; M. De Santis;
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作者单位

Laboratoire de Cristallographie, CNRS, Boite Postal 166 X, 38 042 Grenoble Cedex 9, France;

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原文格式 PDF
正文语种 eng
中图分类固体物理学;
关键词
thin film structure and morphology; X-ray diffraction; self-organized systems;

机译：薄膜的结构和形态;X射线衍射;自组织系统;

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1. Two-Dimensional Hydrogen Bond Networks Supported by CH/π Interaction Leading to a Molecular Packing Appropriate for Topochemical Polymerization of 1,3-Diene Monomers [J] . Sadamu Nagahama, Katsunari Inoue, Kazuki Sada, Crystal growth & design . 2003,第2期

机译：CH /π相互作用支持的二维氢键网络导致适合于1,3-二烯单体拓扑化学聚合的分子堆积
2. The evaluation of the role of C-H center dot center dot center dot F hydrogen bonds in crystal altering the packing modes in the presence of strong hydrogen bond [J] . Kaur Gurpreet, Singh Sandhya, Sreekumar Amritha, Journal of Molecular Structure . 2016,第Null期

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4. The important roles of hydrogen bond network in ligand-receptor interactions:a molecular dynamics simulation study [C] . Dechang Li, Baohua Ji, Keh-Chih Hwang, 13th International conference on fracture . 2013

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5. The interaction of strong hydrogen-bonding molecules with the surface of ice nanocrystals. [D] . Delzeit, Lance Dean. 1997

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7. Interplay between Hydrogen Bonding and Molecule-Substrate Interactions in the Case of Terephthalic Acid Molecules on Cu(001) Surfaces [O] . Fuhr, Javier Daniel, Carrera, Alvaro Daniel, Murillo Quiros, Natalia Maria, 2017

机译：在Cu（001）表面上对苯二甲酸分子的情况下，氢键与分子-底物相互作用之间的相互作用

Role of hydrogen interaction in two-dimensional molecular packing with strong molecule-substrate bonding

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