Thermo-cleavable polymers: Materials with enhanced photochemical stability

Matthieu Manceau; Martin Helgesen; Frederik C. Krebs

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Thermo-cleavable polymers: Materials with enhanced photochemical stability

机译：热裂解聚合物：具有增强的光化学稳定性的材料

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Photochemical stability of three thermo-cleavable polymers was investigated as thin films under atmospheric conditions. A significant increase in lifetime was observed once the side-chain was cleaved emphasizing the detrimental effect of solubilizing groups on the photochemical stability of conjugated polymers. In addition to their ease of processing, thermo-cleavable polymers thus also offer a greater intrinsic stability under illumination.

机译：在大气条件下以薄膜形式研究了三种热裂解聚合物的光化学稳定性。一旦侧链断裂，观察到寿命显着增加，强调了增溶基团对共轭聚合物的光化学稳定性的不利影响。因此，除了易于加工之外，热裂解聚合物在光照下还具有更大的固有稳定性。

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《Polymer Degradation and Stability》 |2010年第12期|p.2666-2669|共4页
作者
Matthieu Manceau; Martin Helgesen; Frederik C. Krebs;
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作者单位

Rise National Laboratory for Sustainable Energy, Technical University of Denmark, P.O. Box 49, DK-4000 Roskilde, Denmark;

Rise National Laboratory for Sustainable Energy, Technical University of Denmark, P.O. Box 49, DK-4000 Roskilde, Denmark;

Rise National Laboratory for Sustainable Energy, Technical University of Denmark, P.O. Box 49, DK-4000 Roskilde, Denmark;

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正文语种 eng
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关键词
thermo-cleavable conjugated polymers; side-chain cleavage; photochemical stability; organic photovoltaics; UV-visible absorbance;

机译：热裂解共轭聚合物;侧链裂解;光化学稳定性;有机光伏;紫外线可见吸收;

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Thermo-cleavable polymers: Materials with enhanced photochemical stability

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