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Temperature dependence of the inversion degree in three-cation spinel solid solutions: experimental evaluation by XRD

机译:三阳离子尖晶石固溶体中转化度的温度依赖性:XRD实验评估

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摘要

The method of degree of inversion calculation presented in the present paper was based on the determination of several temperature-dependent parameters such as: oxygen positional parameter, lattice parameter, cation site occupancies, and a cation-anion distance in tetrahedral and octahedral sites. The theoretical basis of the method as well as the required derivation of formulae and the conditions of its application has been described.
机译:本文提出的反演度计算方法是基于几个温度相关参数的确定,这些参数包括:氧位置参数,晶格参数,阳离子位点占有率以及四面体和八面体位点的阳离子-阴离子距离。已经描述了该方法的理论基础以及所需的公式推导及其应用条件。

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