Cu-catalyzed cross-dehydrogenative coupling: A versatile strateav for C-C bond formations via the oxidative activation of sp(3) C-H bonds

Li ZP; Bohle DS; Li CJ

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Cu-catalyzed cross-dehydrogenative coupling: A versatile strateav for C-C bond formations via the oxidative activation of sp(3) C-H bonds

机译：铜催化的交叉脱氢偶联：通过sp（3）C-H键的氧化活化C-C键形成的通用策略

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摘要

Cu-catalyzed cross-dehydrogenative coupling (CDC) methodologies were developed based on the oxidative activation of sp(3) C-H bonds adjacent to a nitrogen atom. Various sp, sp(2), and sp(3) C-H bonds of pronucleophiles were used in the Cu-catalyzed CDC reactions. Based on these results, the mechanisms of the CDC reactions also are discussed.

机译：铜催化的交叉脱氢偶联（CDC）方法是基于与氮原子相邻的sp（3）C-H键的氧化活化而开发的。亲核试剂的各种sp，sp（2）和sp（3）C-H键用于Cu催化的CDC反应中。基于这些结果，还讨论了CDC反应的机理。

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《Proceedings of the National Academy of Sciences of the United States of America》 |2006年第24期|p. 8928-8933|共6页
作者
Li ZP; Bohle DS; Li CJ;
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作者单位

McGill Univ, Dept Chem, Montreal, PQ H3A 2K6, Canada;

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收录信息美国《科学引文索引》(SCI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
原文格式 PDF
正文语种 eng
中图分类自然科学总论;
关键词
C-H activation; catalysis; Baylis-Hillman reaction; Mannich reaction; Friedel-crafts reaction; BAYLIS-HILLMAN REACTION; CATION POOL METHOD; NITROGEN ATOM; TERMINAL ALKYNES; ENANTIOSELECTIVE SYNTHESIS; ASYMMETRIC CATALYSIS; PROPARGYLIC AMINES; MANNICH REACTION; TERTIARY-AMINES; DIRECT ADDITION;

机译：CH活化;催化;Baylis-Hillman反应;Mannich反应;Friedel-crafts反应;BAYLIS-Hillman反应;阳离子池法;氮原子;末端烷基;对映选择性合成;不对称催化;亲酰胺基;曼尼奇反应;叔丁基加成;

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专利

1. Metal-free oxidative C-C bond formation of active methylenic sp~3 C-H bonds with benzylic sp~3 C-H and allylic sp~3 C-H bonds mediated by DDQ. [J] . D. Ramesh, U. Ramulu, S. Rajaram Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2010,第37期

机译：DDQ介导的活性亚甲基sp〜3 C-H键与苄基sp〜3 C-H和烯丙基sp〜3 C-H键的无金属氧化C-C键形成。
2. A Reaction for sp~3-sp~3 C-C Bond Formation via Cooperation of Lewis Acid-Promoted/Rh-Catalyzed C-H Bond Activation [J] . Lei Shi, Yong-Qiang Tu, Min Wang, Journal of the American Chemical Society . 2005,第31期

机译：通过路易斯酸促进/ Rh催化的C-H键活化的相互作用形成sp〜3-sp〜3 C-C键的反应
3. C-H Bond Activation and Subsequent C-C Bond Formation Promoted by Osmium:2-Vinylpyridine-Acetylene Couplings [J] . Miguel A.Esteruelas, Francisco J.Fernandez-Alvarez, Montserrat Olivan, Journal of the American Chemical Society . 2006,第14期

机译：O：2-乙烯基吡啶-乙炔偶联促进的C-H键活化和随后的C-C键形成
4. Ru/CeO2-Catalyzed C-C Bond Forming Reactions via Aromatic C-H Bond Activation [C] . Kenji Wada, Hiroki Miura, Saburo Hosokawa Symposium on Organometallic Chemistry . 2008

机译：Ru / CeO2催化的C-C键通过芳族C-H键活化形成反应
5. C-H bond activation and C-C bond formation at adjacent metals. [D] . Torkelson, Jeffrey Robert. 1998

机译：在相邻金属处的C-H键活化和C-C键形成。
6. Cu-catalyzed cross-dehydrogenative coupling: A versatile strategy forC–C bond formations via the oxidative activation of sp3C–H bonds [O] . Zhiping Li, D. Scott Bohle, Chao-Jun Li 2006

机译：铜催化的交叉脱氢偶联：一种通用的策略通过sp3的氧化活化形成CC键碳氢键
7. Cu-catalyzed cross-dehydrogenative coupling: A versatile strategy for C–C bond formations via the oxidative activation of sp3 C–H bonds [O] . Li, Zhiping, Bohle, D. Scott, Li, Chao-Jun 2006

机译：铜催化的交叉脱氢偶联：通过sp3 C–H键的氧化活化形成CC键的通用策略

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Cu-catalyzed cross-dehydrogenative coupling: A versatile strateav for C-C bond formations via the oxidative activation of sp(3) C-H bonds

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