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Concentration of renewable products of crude bio-oil from thermal cracking of the methyl esters in castor oil

机译:蓖麻油中甲酯的热裂解产生的粗制生物油可再生产品的浓度

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Castor oil has been widely used as raw material to obtain compounds such as paints, solvents, rubbers, polyurethane polymers and chemical inputs. Then, one highlighted route is thermal cracking of castor oil to produce bio-oil, mainly composed of heptaldehyde and methyl undecenoate, which are used as precursors of lactones in the food and beverage industry. The main aim of this study was to evaluate the separation heptaldehyde and methyl undecenoate by distillation of bio-oil from thermal cracking of the methyl esters in castor oil (MECO). Distilled fractions were analyzed by gas chromatography (GC). Thus, it was possible to concentrate the fractions of heptaldehyde and methyl undecenoate in a section with a distillation system at atmospheric pressure with a distillation rate of 5.0 mL min(-1) at 270 degrees C, which motivates new researches for up-scaling of the process. (C) 2019 Elsevier Ltd. All rights reserved.
机译:蓖麻油已被广泛用作获得诸如油漆,溶剂,橡胶,聚氨酯聚合物和化学原料的化合物的原料。然后,一种突出的途径是将蓖麻油热裂解以生产生物油,该生物油主要由庚醛和十一碳烯酸甲酯组成,在食品和饮料工业中用作内酯的前体。这项研究的主要目的是评估从蓖麻油中的甲酯的热裂解中分离出的生物油,通过蒸馏分离生物油中的七醛和十一碳烯酸甲酯(MECO)。通过气相色谱法(GC)分析馏分。因此,可以在常压蒸馏系统中以270°C的5.0 mL min(-1)的蒸馏速率将馏分中的庚醛和十一碳烯酸甲酯浓缩,这激发了新的研究规模。过程。 (C)2019 Elsevier Ltd.保留所有权利。

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