Syntheses and structures of highly soluble bis(ethylenedithio)tetrathiafulvalene molecules with alkyl chains

I. Aoyagi; M. Katsuhara; T. Mori

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Syntheses and structures of highly soluble bis(ethylenedithio)tetrathiafulvalene molecules with alkyl chains

机译：具有烷基链的高可溶性双（亚乙基二硫代）四硫富瓦烯分子的合成与结构

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Bis(ethylenedithio)tetrathiafulvalene (ET) molecules with one alkyl chain, C_nET (n = 1-6) are synthesiszed. The solubility in usual organic solvents is remarkably improved without changing the electron donating ability, and good thin films are formed by the solution cast method. C_1ET has the same dimer structure as ET, while the structures of the n = 2-4 molecules are composed of zig-zag columns.

机译：合成了具有一个烷基链的双（亚乙基二硫代）四硫富瓦烯（ET）分子C_nET（n = 1-6）。在不改变给电子能力的情况下，在常规有机溶剂中的溶解度得到显着提高，并且通过溶液流延法形成了良好的薄膜。 C_1ET具有与ET相同的二聚体结构，而n = 2-4分子的结构由之字形列组成。

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《Science and Technology of Advanced Materials》 |2004年第4期|p.443-447|共5页
作者
I. Aoyagi; M. Katsuhara; T. Mori;
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作者单位

Department of Organic and Polymeric Materials, Graduate School of Science and Engineering, Tokyo Institute of Technology, O-okayama, Meguroku, Tokyo 152-8552, Japan;

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正文语种 eng
中图分类工程材料学;
关键词
synthesis; thin films; organic conductors; AFM; crystal structure;

机译：合成;薄膜;有机导体;原子力显微镜;晶体结构;

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专利

1. Syntheses and structures of highly soluble bis(ethylenedithio)tetrathiafulvalene molecules with alkyl chains [J] . Science and technology of advanced materials . 2004,第4期

机译：具有烷基链的高可溶性双（亚乙基二硫代）四硫富瓦烯分子的合成与结构
2. Syntheses, structures, and electroconductivity of bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF) and bis(methylenedithio)tetrathiafulvalene (BMDT-TTF) salts with cobalt 8,8 '-dichloro-3,3 '-bis(1,2-dicarbollide) [J] . Kazheva O. N., Kravchenko A. V., Aleksandrov G. G., Russian Chemical Bulletin . 2014,第6期

机译：双（亚乙基二硫代）四硫富瓦烯（BEDT-TTF）和双（亚甲基二硫代）四硫富瓦烯（BMDT-TTF）盐与钴的8,8'-dichloro-3,3'-双（1,2-二咔唑）钴的合成，结构和导电性）
3. Novel ET-coordinated copper(I) complexes: Syntheses, structures, and physical properties (ET = BEDT-TTF = bis(ethylenedithio)tetrathiafulvalene) [J] . Kanehama R., Umemiya M., Iwahori F., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2003,第22期

机译：新型ET配位的铜（I）配合物：合成，结构和物理性质（ET = BEDT-TTF =双（乙烯二硫代）四硫富瓦烯
4. Metallic, Insulating and Superconducting States in κ-ET_2X Systems, where ET is the BEDT- TTF (bis(ethylenedithio)tetrathiafulvalene) molecule [C] . International winterschool on electronic properties of novel materials - progress in molecular nanostructures . 1998

机译：κ-et_2x系统中的金属，绝缘和超导状态，其中ET是床位 - TTF（双（乙基硫代）四硫甲炔）分子
5. Studies on Syntheses and Properties of Organic Transition Metal Complexes wlth Long Alkyl Chains [D] . 太田, 和親 1981

机译：长烷基链有机过渡金属配合物的合成与性能研究
6. Regioselective synthesis of chiral dimethyl-bis(ethylenedithio)tetrathiafulvalene sulfones [O] . Flavia Pop, Narcis Avarvari 2015

机译：区域选择性合成手性二甲基-双（亚乙基二硫代）四硫富瓦烯砜
7. The Intermolecular Interaction of Tetrathiafulvalene and Bis(ethylenedithio)tetrathiafulvalene in Organic Metals. Calculation of Orbital Overlaps and Models of Energy-band Structures [O] . Takehiko Mori, Akiko Kobayashi, Yukiyoshi Sasaki, 1984

机译：四苯甲戊戊烯和双（乙基硫代）四苯甲烯在有机金属中的分子间相互作用。轨道重叠和节能结构模型的计算
8. Vibrational studies of (sup 13)C- and (sup 34)S-labelled bis(ethylenedithio)tetrathiafulvalene (ET) donor molecule [R] . Ferraro, J R, Kini, A M, Williams, J M, 1994

机译：（sup 13）C-和（sup 34）s-标记的双（亚乙基二硫代）四硫富瓦烯（ET）供体分子的振动研究

Syntheses and structures of highly soluble bis(ethylenedithio)tetrathiafulvalene molecules with alkyl chains

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