Comparison of electronic structures of orthorhombic and hexagonal manganites studied by X-ray absorption spectroscopy

Asokan K; Dong CL; Bao CW; Tsai HM; Chiou JW; Chang CL; Pong WF; Duran P; Moure C; Pena O

首页> 外文期刊>Solid State Communications >Comparison of electronic structures of orthorhombic and hexagonal manganites studied by X-ray absorption spectroscopy

【24h】

Comparison of electronic structures of orthorhombic and hexagonal manganites studied by X-ray absorption spectroscopy

机译：X射线吸收光谱法研究正交晶和六方锰矿的电子结构

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Electronic structures of orthorhombic perovskite-type manganites (OM) and hexagonal manganites (HM) are compared by using X-ray absorption near edge structure spectroscopy. This study reveals that the environments around Mn and O ions in both the systems are different. These are reflected primarily in the lifting of degeneracy of the Mn 3d orbitals. Interestingly, the unoccupied Mn 3d(x)(-y)(2)(2) orbital in HM is strongly hybridized with O 2p states and appears to be responsible for both long range orderings: ferroelectnic ordering at high temperatures and ferromagnetic ordering at low temperatures. (c) 2005 Elsevier Ltd. All rights reserved.

机译：正交晶钙钛矿型锰矿（OM）和六角型锰矿（HM）的电子结构通过使用近边缘结构的X射线吸收光谱进行了比较。这项研究表明，两个系统中Mn和O离子周围的环境是不同的。这些主要反映在Mn 3d轨道简并性的解除上。有趣的是，HM中未占据的Mn 3d（x）（-y）（2）（2）轨道与O 2p态高度杂化，似乎与两种长程有序有关：高温下的铁电有序和低温下的铁磁有序温度。（c）2005 Elsevier Ltd.保留所有权利。

著录项

来源
《Solid State Communications》 |2005年第12期|p. 821-826|共6页
作者
Asokan K; Dong CL; Bao CW; Tsai HM; Chiou JW; Chang CL; Pong WF; Duran P; Moure C; Pena O;
展开▼
作者单位

Tamkang Univ, Dept Phys, Tamkang, Taiwan;

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类固体物理学;
关键词
manganites; XANES; electronic structure; X-ray absorption spectroscopy; YMNO3; TRANSITION; EDGES;

机译：锰矿;XANES;电子结构;X射线吸收光谱;YMNO3;转变;边缘;

相似文献

外文文献
中文文献
专利

1. Electron- and hole-doping effects on the electronic structure of manganite studied by X-ray absorption spectroscopy [J] . Asokan K, Jan JC, Rao KVR, Journal of Physics. Condensed Matter . 2004,第21期

机译：X射线吸收光谱研究电子和空穴掺杂对锰电子结构的影响
2. Effect of Co, Ni, and Cu substitution on the electronic structure of hexagonal YMnO_3 studied by x-ray absorption spectroscopy [J] . K. Asokan, Y. S. Chen, C. W. Pao, Applied Physicsletters . 2009,第13期

机译：X射线吸收光谱研究Co，Ni和Cu取代对六角型YMnO_3电子结构的影响
3. Electronic structure of Fe2P(10(1)over-bar0) studied by soft X-ray photoelectron spectroscopy and X-ray absorption spectroscopy [J] . Sugizaki Y., Motoyama H., Edamoto K., Surface Science . 2017,第octa期

机译：软X射线光电子能谱和X射线吸收光谱法研究Fe2P（10（1）over-bar0）的电子结构
4. Electronic Structures of Hexagonal Manganites HoMnO_3 Studied by X-ray Absorption Near-edge Structure [C] . K. Asokan, C. L. Dong, C. W. Bao, International Conference on Synchrotron Radiation Instrumentation . 2007

机译：X射线吸收近边缘结构研究六边形锰酯Homno_3的电子结构
5. Interrogating the Electronic Structure and Photochemistry of Molecules with Transient X-ray Absorption Spectroscopy [D] . Van Kuiken, Benjamin Evert 2014

机译：瞬态X射线吸收光谱法研究分子的电子结构和光化学
6. X-ray absorption spectroscopy by full-field X-ray microscopy of a thin graphite flake: Imaging and electronic structure via the carbon K-edge [O] . Carla Bittencourt, Adam P Hitchock, Xiaoxing Ke, 2012

机译：薄石墨片的全场X射线显微镜X射线吸收光谱法：通过碳K边缘成像和电子结构
7. Effect of Co, Ni, and Cu substitution on the electronic structure of hexagonal YMnO3 studied by x-ray absorption spectroscopy [O] . Asokan, K., Peña, Octavio, Moure Jiménez, Carlos 2013

机译：X射线吸收光谱研究Co，Ni和Cu取代对六角型YMnO3电子结构的影响

Comparison of electronic structures of orthorhombic and hexagonal manganites studied by X-ray absorption spectroscopy

摘要

著录项

相似文献

相关主题

期刊订阅