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Electronic transport in amorphous carbon nitride (a-CN_x:H) and carbon oxide (a-CO_x:H) films

机译:非晶氮化碳(a-CN_x:H)和氧化碳(a-CO_x:H)膜中的电子传输

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摘要

The dielectric properties of a-CN_x:H and a-CO_x:H thin films have been investigated using ohmic σ(T) and field-dependent σ(F) electrical conductivity measurements. A lower density of electronic states in carbon oxides has been inferred from the Ln(σ) ≈ T~(-1/4) behavior, consistent with a hopping mechanism. The dielectric constant ε values deduced from the Poole-Frenkel field-dependence are found to decrease (increase) with increasing oxygen (nitrogen) content. Using refractive index values obtained from ellipsometry, a good agreement between ε and n~2 is found for the oxygen-rich (18-20%) alloys, having values of ε ~ 1.9-2.3, which could be considered as a new low dielectric constant material.
机译:已使用欧姆σ(T)和场相关σ(F)电导率测量研究了a-CN_x:H和a-CO_x:H薄膜的介电性能。从Ln(σ)≈T〜(-1/4)行为可以推断出碳氧化物中较低的电子态密度,这与跳变机制一致。发现由Poole-Frenkel场相关性推导的介电常数ε值随着氧(氮)含量的增加而降低(增加)。使用椭圆偏振法获得的折射率值,发现富氧(18-20%)合金的ε和n〜2之间具有良好的一致性,其值ε〜1.9-2.3,可以认为是一种新的低介电常数恒定的材料。

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