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Effect Of Carbonization Temperature On The Structure Of Carbon Nanofiber Nonwovens By Electrospinning

机译:碳化温度对静电纺丝碳纳米纤维非织造布结构的影响

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Polyacrylonitrile (PAN) nanofibers were manufactured by electrospinning. PAN nanofiber mats were peroxidized at 250 ℃ and carbonized at different temperatures. Thus carbon nanofiber web was obtained. X-ray diffraction and Raman spectroscopy were used to investigate the structural of carbon nanofibers. The electrical conductivities of carbon nanofibers webs were measured by the four-point probe method. The research results indicate that with the temperature rising, the crystallite dimensions (Lc) and the graphite mole fraction (La) gradually increase and the conductivity of carbon nanofiber webs become better. There is a linear relationship between the graphite mole fraction (La) and electrical conductivity of carbon nanofiber web.
机译:聚丙烯腈(PAN)纳米纤维是通过静电纺丝制造的。 PAN纳米纤维垫在250℃过氧化并在不同温度下碳化。由此获得碳纳米纤维网。用X射线衍射和拉曼光谱研究碳纳米纤维的结构。碳纳米纤维网的导电率通过四点探针法测量。研究结果表明,随着温度的升高,微晶尺寸(Lc)和石墨摩尔分数(La)逐渐增大,碳纳米纤维网的电导率逐渐提高。石墨摩尔分数(La)与碳纳米纤维网的电导率之间存在线性关系。

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