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Electrodeposition of CuInSe_2 thin films onto Mo-glass substrates

机译:CuInSe_2薄膜在Mo-玻璃衬底上的电沉积

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摘要

The mechanism of the underpotential electrodeposition of copper indium diselenide (CIS) in the presence of an excess of In~(3+) was studied. It was found that the value of indium and copper ratio (In/Cu) in the films electrodeposited in the potentials area from - 0.2 to - 0.6 V (vs. SCE) is independent of the concentration ratio of Cu~(2+)/In~(3+). At the same time, the concentration of indium in the films obtained is determined both by the deposition potential and the ratio of Se(IV)/Cu~(2+) in the solution. The proposed model provides the list of the formed compounds as a function of the solution concentration and the applied potential.
机译:研究了在过量的In〜(3+)存在下铜铟二硒化物(CIS)欠电沉积的机理。发现电沉积在-0.2至-0.6 V(vs. SCE)的电位区域中的薄膜中铟和铜之比(In / Cu)的值与Cu〜(2 +)/在〜(3+)。同时,所获得的膜中铟的浓度取决于沉积电位和溶液中Se(IV)/ Cu〜(2+)的比值。建议的模型提供了所形成化合物的列表,该列表是溶液浓度和所施加电势的函数。

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