Limiting current of zinc electrodeposition from zincate solution with the additive of polymeric tetraalkylammonium salt

Trophymenko V.V.; Medvedeva I.A.; Gaponov A.A.

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Limiting current of zinc electrodeposition from zincate solution with the additive of polymeric tetraalkylammonium salt

机译：聚合四烷基铵盐添加剂限制锌酸盐溶液电沉积锌的电流

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By means of determination of activation energy for zinc electrodeposition process from zincate solution with the additive of polymeric tetraalky lammonium salt it has been shown that the exceeding of electrocrystallization current above limiting diffusion current in the additive-free solution is caused by the intensification of convective transfer of zinc ions by evolved hydrogen. The formation of bright zinc deposis in the region of limiting diffusion current has been explained by the inhibition of zinc nuclei growth in the presence of additive.

机译：通过测定锌盐溶液与聚合物四烷基铵盐的添加剂在锌电沉积过程中的活化能，结果表明，在无添加剂的溶液中，电结晶电流超过极限扩散电流的原因是对流转移的加剧氢释放出的锌离子。在存在添加剂的情况下，通过抑制锌核的生长，可以解释在极限扩散电流区域内亮锌脱垂的形成。

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《Украинский химический журнал》 |1999年第2期|p.114-118|共5页
作者
Trophymenko V.V.; Medvedeva I.A.; Gaponov A.A.;
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收录信息美国《科学引文索引》(SCI);
原文格式 PDF
正文语种 rus
中图分类化学;
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Limiting current of zinc electrodeposition from zincate solution with the additive of polymeric tetraalkylammonium salt

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