Kinetic regularities in the alkylation of sodium acetate by butyl bromide in dipolar nonhydroxyl solvents

Lyavinets A.S.

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Kinetic regularities in the alkylation of sodium acetate by butyl bromide in dipolar nonhydroxyl solvents

机译：在偶极非羟基溶剂中溴化丁基溴对乙酸钠烷基化的动力学规律

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Kinetics of alkylation of sodium acetate by butyl bromide has been investigated in dipolar non-hydroxylic solvents. It has been found the reaction is realized with the first order on each reactant. The effect of a number of solvents on the reaction has been studied. The rate of alkylation and degree of transformation of reactants have been established to raise with the increase of solvents' nucleophilic properties. Hexamethylphosphoramide is the best solvent for this reaction.

机译：已经在偶极非羟基溶剂中研究了丁基溴使乙酸钠烷基化的动力学。已经发现反应是在每种反应物上以第一级实现的。已经研究了多种溶剂对反应的影响。已经建立了烷基化速率和反应物的转化程度，以随着溶剂的亲核性质的增加而提高。六甲基磷酰胺是该反应的最佳溶剂。

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《Украинский химический журнал》 |1998年第3期|p.49-51|共3页
作者
Lyavinets A.S.;
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收录信息美国《科学引文索引》(SCI);
原文格式 PDF
正文语种 rus
中图分类化学;
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Kinetic regularities in the alkylation of sodium acetate by butyl bromide in dipolar nonhydroxyl solvents

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