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Toxicological analysis of ceramic building materials - Tiles and glasses - Obtained from post-treated bottom ashes

机译:陶瓷建筑材料的毒理学分析-瓷砖和玻璃-从后处理的底灰获得

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In Italy, the production of bottom ash from waste incineration was estimated as 1.6 million tons/year, corresponding to 30% of the total input waste. The bottom ash is mainly formed by SiO2, Al2O3, CaO, Na2O and low amount of heavy metals, therefore it cannot be considered 'non-hazardous' waste. In this context, the aim of this work was to determine the effectiveness of the sintering and vitrification techniques to turn bottom ash into an inert ceramic or glass matrix using toxicological tests. The bottom ash from a municipal solid waste facility was ground and used in ceramic tile and glass compositions. After sintering of the ceramic tiles and melting of the glass compositions, the samples were characterized by leachability and toxicological analyzes. Living organisms were used in the toxicological tests, Escherichia coli and Staphylococcus aureus (Agar Diffusion Test), Anemia sp. (Acute Toxicity Test) and Lactuca sativa (germination) and the results were compared with the plasmid DNA test. Regarding the leachability results, the ceramic tile samples showed a concentration of Cu slightly above the limit determined by the D.M. 5/4/2006 directive and, therefore, could not be considered an inert material. Regarding the toxicological tests, the bottom ash alone is mutagenic, but this effect is avoided once the ash is immobilized into the glasses and ceramic tiles, as demonstrated by the results reported in this study. (C) 2019 Elsevier Ltd. All rights reserved.
机译:在意大利,废物焚烧产生的底灰产量估计为160万吨/年,相当于总输入废物的30%。底灰主要由SiO2,Al2O3,CaO,Na2O和少量重金属组成,因此不能视为“无害”废物。在这种情况下,这项工作的目的是使用毒理学试验确定烧结和玻璃化技术将底灰转化为惰性陶瓷或玻璃基体的有效性。将来自市政固体废物设施的底灰粉碎并用于瓷砖和玻璃组合物中。烧结陶瓷砖并融化玻璃组合物后,通过浸出性和毒理学分析对样品进行表征。在毒理学测试中使用了活生物体,包括大肠杆菌和金黄色葡萄球菌(琼脂扩散测试),贫血菌。 (急性毒性试验)和苜蓿(发芽),并将结果与​​质粒DNA试验进行比较。关于浸出性结果,瓷砖样品显示的铜浓度略高于D.M.所确定的极限。 5/4/2006指令,因此不能被视为惰性材料。关于毒理学测试,仅底部灰烬是诱变的,但如本研究报告的结果所示,一旦将灰烬固定在玻璃和瓷砖上,就可以避免这种影响。 (C)2019 Elsevier Ltd.保留所有权利。

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