Mixed ion effect and Na-23 NMR spectra of copper substituted NASICON Cu1-yNa0.2+yZr1.9Mg0.1(PO4)(3)

Fujimoto H.; Ohara K.; Zou Y.; Yamamura R.; Inoue N.

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Mixed ion effect and Na-23 NMR spectra of copper substituted NASICON Cu1-yNa0.2+yZr1.9Mg0.1(PO4)(3)

机译：铜取代的NASICON Cu1-yNa0.2 + yZr1.9Mg0.1（PO4）（3）的混合离子效应和Na-23 NMR光谱

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We presented the conductivity, X-ray diffraction and Na-23 NMR spectra of Cu1-yNa0.2+yZr1.9Mg0.1 (PO4)(3) with Na and Cu mixed ions defined as ionic ratio i = [Na]/{[Na] + [Cu]}. Lattice parameters a axis decreased linearly with increasing ionic ratio and c axis increased linearly with increasing ionic ratio. Conductivity against ionic ratio showed a minimum around i = 0.8. NMR spectra of Na-23 nucleus showed a strong quadrupole interaction. The quadrupole coupling constant showed an anomaly around i = 0.8. We observed new results on the mixed ion effect. (C) 2002 Elsevier Science B.V All rights reserved. [References: 12]

机译：我们介绍了Cu1-yNa0.2 + yZr1.9Mg0.1（PO4）（3）的电导率，X射线衍射和Na-23 NMR光谱，其中Na和Cu混合离子定义为离子比i = [Na] / { [Na] + [Cu]}。晶格参数a轴随着离子比率的增加而线性减少，而c轴随着离子比率的增加而线性增加。电导率对离子比率的最小值在i = 0.8附近。 Na-23核的NMR光谱显示很强的四极相互作用。四极偶合常数在i = 0.8附近显示出异常。我们观察到有关混合离子效应的新结果。（C）2002 Elsevier Science B.V保留所有权利。 [参考：12]

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《Physics Letters, A》 |2002年第5期|共6页
作者
Fujimoto H.; Ohara K.; Zou Y.; Yamamura R.; Inoue N.;
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正文语种 eng
中图分类物理学;
关键词
Ionic conductivity; Hexagonal parameters; Mixed ion effect; Nasicon; Quadrupole coupling constant; Alkali;

机译：离子电导率;六角参数;混合离子效应;Nasicon;四极偶合常数;碱;

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1. Mixed ion effect and Na-23 NMR spectra of copper substituted NASICON Cu1-yNa0.2+yZr1.9Mg0.1(PO4)(3) [J] . Fujimoto H., Ohara K., Zou Y., Physics Letters, A . 2002,第5期

机译：铜取代的NASICON Cu1-yNa0.2 + yZr1.9Mg0.1（PO4）（3）的混合离子效应和Na-23 NMR光谱
2. IR AND ~1H NMR SPECTRAL STUDIES OF SOME MIXED-LIGAND PHOSPHINE COMPLEXES OF RUTHENIUM(II) WITH 1-PHENYL SUBSTITUTED DERIVATIVES OF TETRAZOLINE-5-THIONE [J] . R. N. PANDEY, PRASHASTI PANDE, R. N. SHARMA Acta Ciencia Indica . 2009,第2期

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4. The preparation of NASICON-type solid electrolyte lithium-ion Li_(1+x)AlxGe_(0.2)Ti_(1.8-x)(PO4)3 by conventional solid-state method [C] . X F Shang, J H Zhang, S Cheng International Workshop on Materials Science and Mechanical Engineering . 2019

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5. Copper NQR and NMR study of metal-substituted yttrium barium(2) copper(3) oxygen(7) and yttrium barium(2) copper(4) oxygen(8). [D] . Cheng, Show-Jye. 1995

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Mixed ion effect and Na-23 NMR spectra of copper substituted NASICON Cu1-yNa0.2+yZr1.9Mg0.1(PO4)(3)

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