...
首页> 外文期刊>Physical review, E. Statistical physics, plasmas, fluids, and related interdisciplinary topics >Metastability in fluctuation-driven first-order transitions: Nucleation of lamellar phases
【24h】

Metastability in fluctuation-driven first-order transitions: Nucleation of lamellar phases

机译:波动驱动的一阶跃迁中的亚稳态:层状相的成核

获取原文
获取原文并翻译 | 示例
           

摘要

The nucleation of a lamellar phase from a supercooled homogeneous phase in a fluctuation-driven first-order transition is studied, based on a phenomenological free energy due to Brazovskii (Zh. Eksp. Teor. Fiz. 68, 175 (1975) [Sov. Phys. JETP 41, 85 (1975)]). The absence of phase coexistence in the corresponding mean-field approximation makes application of the standard droplet theory of homogeneous nucleation problematic. A self-consistent coarse-graining procedure is introduced to overcome this difficulty, and the barrier height for nucleation of a critical droplet is estimated in the weak-coupling limit. Contrary to earlier estimates, the critical droplet shape is shown to be anisotropic in general. Some effects of distortions and defects in the lamellar structure are considered and are shown to affect the critical droplet only very near coexistence, where the probability of nucleation vanishes. The coarse-graining procedure introduced here follows from a novel application of the momentum-shell renormalization-group method to systems in the Brazovskii class. Possible applications of the theory to the microphase separation transition in diblock copolymers and to Rayleigh-Bénard convection are briefly discussed.
机译:基于Brazovskii的现象学自由能(Zh。Eksp。Teor。Fiz。68,175(1975)[Sov。 JETP 41,85(1975)]。在相应的平均场近似中不存在相位共存,使得标准液滴理论的均匀成核问题的应用成为问题。为了克服这个困难,引入了自洽的粗粒度过程,并且在弱耦合极限中估计了临界液滴成核的势垒高度。与早期的估计相反,临界液滴的形状总体上是各向异性的。考虑了层状结构中变形和缺陷的某些影响,并显示它们仅在非常接近共存的情况下才影响临界液滴,在这种情况下,成核的可能性就消失了。这里引入的粗粒度过程是根据动量壳重整化组方法在Brazovskii类系统中的新颖应用而得出的。简要讨论了该理论在二嵌段共聚物中的微相分离过渡以及在Rayleigh-Bénard对流中的可能应用。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号