Three-dimensional periodic lattice of ZrO_2 nanocrystals in transparent silica matrix

Masalov V.M.; Zhokhov A.A.; Gorelik V.S.; Kudrenko E.A.; Shteǐnman E.A.; Tereshchenko A.N.; Maksimuk M.Y.; Bazhenov A.V.; Zverkova I.I.; Emelchenko G.A.

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Three-dimensional periodic lattice of ZrO_2 nanocrystals in transparent silica matrix

机译：透明二氧化硅基质中ZrO_2纳米晶体的三维周期性晶格

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The conditions for synthesizing an opal-zirconia-carbon nanocomposite in the form of monolithic (without pores) transparent silica with an ordered distribution of nanocrystals throughout the sample have been determined. Zirconia nanocrystals form a three-dimensional periodic lattice of nanoclusters with sizes ranging from several nanometers to several tens of nanometers. This nanocomposite exhibits properties typical of photonic crystals. The samples have been studied using electron microscopy, X-ray diffraction, photoluminescence, and Raman scattering. The structural state and spatial arrangement of zirconia nanocrystals and carbon clusters in the nanocomposite have been elucidated. Optical transmission and optical reflection photoluminescence spectra of the nanocomposites have been measured.

机译：已经确定了用于合成整体式（无孔）透明二氧化硅形式的蛋白石-氧化锆-碳纳米复合材料的条件，其中纳米晶在整个样品中有序分布。氧化锆纳米晶体形成纳米簇的三维周期性晶格，其尺寸范围从几纳米到几十纳米。该纳米复合材料展现出光子晶体的典型特性。使用电子显微镜，X射线衍射，光致发光和拉曼散射对样品进行了研究。已经阐明了氧化锆纳米晶体的结构状态和空间排列以及纳米复合物中的碳簇。已经测量了纳米复合材料的光透射和光反射光致发光光谱。

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《Physics of the solid state》 |2010年第4期|共6页
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Masalov V.M.; Zhokhov A.A.; Gorelik V.S.; Kudrenko E.A.; Shteǐnman E.A.; Tereshchenko A.N.; Maksimuk M.Y.; Bazhenov A.V.; Zverkova I.I.; Emelchenko G.A.;
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1. Three-dimensional periodic lattice of ZrO_2 nanocrystals in transparent silica matrix [J] . Masalov V.M., Zhokhov A.A., Gorelik V.S., Physics of the solid state . 2010,第4期

机译：透明二氧化硅基质中ZrO_2纳米晶体的三维周期性晶格
2. Periodic Mesoporous Hydridosilica-Synthesis of an 'Impossible'Material and Its Thermal Transformation into Brightly Photoluminescent Periodic Mesoporous Nanocrystal Silicon-Silica Composite [J] . Zhuoying Xie, Eric J. Henderson, (OE)mer Dag, Journal of the American Chemical Society . 2011,第13期

机译：周期性介孔氢化硅-“不可能”材料的合成及其热转化为光致发光的周期性介孔纳米晶体硅-二氧化硅复合材料
3. Synthesis of nanocrystal-polymer transparent hybrids via polyurethane matrix grafted onto functionalized CdS nanocrystals [J] . Chen S, Zhu J, Shen YF, Langmuir: The ACS Journal of Surfaces and Colloids . 2007,第26期

机译：通过接枝到功能化的CdS纳米晶体上的聚氨酯基质合成纳米晶体-聚合物透明杂化物
4. Preparation of transparent anatase nanocrystal-dispersed silica films via sol-gel process at low temperatures [C] . Atsunori Matsuda, Osaka Prefecture Univ., Osaka, Conference on sol-gel optics . 2000

机译：低温溶胶-凝胶法制备透明锐钛矿型纳米晶分散二氧化硅薄膜
5. Synthesis and characterization of carbon nanotubes, gold nanorods, silica coated nanocrystals, and binary nanocrystal superlattices [D] . Smith, Danielle Kristin 2009

机译：碳纳米管，金纳米棒，二氧化硅包覆的纳米晶体和二元纳米晶体超晶格的合成与表征
6. Decoupling the refractive index from the electrical properties of transparent conducting oxides via periodic superlattices [O] . David Caffrey, Emma Norton, Cormac Ó Coileáin, -1

机译：通过周期性超晶格将折射率与透明导电氧化物的电学特性解耦
7. Periodic mesoporous hydridosilica-synthesis of an "impossible" material and its thermal transformation into brightly photoluminescent periodic mesoporous nanocrystal silicon-silica composite [O] . Xie, Z., Henderson, E.J., Dag O., 2011

机译：周期性介孔氢化硅的“不可能”材料的合成及其热转化为光致发光的周期性介孔纳米晶体硅-二氧化硅复合材料

Three-dimensional periodic lattice of ZrO_2 nanocrystals in transparent silica matrix

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