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Action of optical radiation on the boundary of a rarefied resonant medium. New possibilities and problems

机译:光辐射在稀薄共振介质边界上的作用。新的可能性和问题

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摘要

The reflection of resonant optical radiation from the boundary of a gaseous medium has long been considered a trivial illustration of the laws of physical optics [1]. The use of this effect for studying the interactions of atoms with one another and with the solid surface became possible only after the experimental discovery [2] and theoretical interpretation [2, 3] of narrow resonances in reflection spectra, free of Doppler broadening. First of all, the resonant collisional broadening in the centers of atomic lines, inaccessible to the standard absorption spectroscopy because of self-absorption effects in optically dense atomic vapors, was determined [4]. The constants of the Van der Waals interaction between a solid surface and a resonantly excited atom, for which other measurement techniques are not known, were also measured [5]. At the same time, inadequacies of the theoretical treatment gave rise to certain problems and paradoxes with interpreting experimental data without proper account for such attendant circumstances as the nonexponential absorption in the medium, deviation of the local field from the mean various factors causing shifts, broadening, and deformation in the spectral contours of the lines of selective mirror reflection.
机译:长期以来,人们一直将共振光辐射从气态介质边界反射回来,这是对物理光学定律的简单说明[1]。仅在通过实验发现[2]和理论解释[2,3]反射光谱中的窄共振而没有多普勒展宽后,才有可能利用这种效应研究原子彼此之间以及与固体表面的相互作用。首先,确定了在原子线中心的共振碰撞加宽,由于在光致密原子蒸气中的自吸收效应,这是标准吸收光谱无法达到的[4]。还测量了固体表面与共振激发原子之间的范德华相互作用的常数,尚无其他测量技术可知[5]。同时,理论处理的不足引起了某些问题和自相矛盾的解释实验数据,而没有适当考虑到伴随的情况,例如介质中的非指数吸收,局部场偏离引起漂移,扩大的平均各种因素。以及选择性镜面反射线的光谱轮廓变形。

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