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Synthesis of aliphatic polyesters of various architectures by the controlled ring-opening polymerization of cyclic esters

机译：通过环酯的受控开环聚合合成各种结构的脂族聚酯

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摘要

A review covering 80 references presents recent studies on the controlled synthesis of poly (aliphatic ester)s (PAE's), mostly including poly (epsilon-caprolactone) and poly (L-lactide). In the introduction, general features and practical applications of PAE's the latter resulting mostly from ability of these polymers to (bio) degradation, are briefly discussed; polymerization methods leading to PAE's are also presented. Then, the ring-opening polymerization of epsilon-caprolactone (CL) and L,L-dilactide (LA), including thermodynamic and kinetic polymerizability of CL and LA is described. Finally, recently elaborated methods of synthesis, of poly (epsilon-caprolactone)s and poly (L-dilactide)s of various architectures, such as linear homopolymers, and star-shaped polymers are presented in a more detail.
机译：涵盖80篇参考文献的综述提供了有关聚（脂族酯）（PAE）受控合成的最新研究，其中大多数包括聚（ε-己内酯）和聚（L-丙交酯）。在简介中，简要讨论了PAE的一般特征和实际应用，后者主要是由这些聚合物的降解能力（生物降解）引起的;还介绍了导致PAE的聚合方法。然后，描述了ε-己内酯（CL）和L，L-二乳酸（LA）的开环聚合，包括CL和LA的热力学和动力学聚合性。最后，更详细地介绍了最近详细阐述的各种结构的聚（ε-己内酯）和聚（L-二丙交酯）的合成方法，例如线性均聚物和星形聚合物。

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