The spin-states and spin-transitions of mononuclear iron(II) complexes of nitrogen-donor ligands

Halcrow MA

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The spin-states and spin-transitions of mononuclear iron(II) complexes of nitrogen-donor ligands

机译：氮供体配体的单核铁（II）配合物的自旋态和自旋转变

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A survey of mononuclear iron(II) complexes with heterocyclic N-donor ligation is presented. A brief introduction to spin-crossover chemistry and low-temperature spin-trapping is provided, since many of these compounds undergo thermal spin-transitions upon cooling or heating. These are highlighted, and the structural changes underlying spin-crossover are discussed where this is known. Materials showing spin-trapping behaviour following thermal quenching or irradiation at very low temperatures are also described. (c) 2007 Elsevier Ltd. All rights reserved.

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《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |2007年第14期|共54页
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Halcrow MA;
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正文语种 eng
中图分类化学;
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n-donor ligands; iron complexes; spin-crossover; magnetic measurements; crystallography; X-RAY-ABSORPTION; LANGMUIR-BLODGETT-FILM; PHOTOINDUCED PHASE-TRANSITION; NUCLEAR INELASTIC-SCATTERING; SYNCHROTRON POWDER-DIFFRACTION; INTERSYSTEM CROSSING DYNAMICS; DEBYE-WALLER FACTORS; QUINQUEDENTATE MACROCYCLIC LIGANDS; FE-57 MOSSBAUER EMISSION; C BOND FORMATION;

机译：正电子配体;铁配合物;自旋交叉;磁性测量;晶体学;X射线吸收;朗格缪尔·布洛杰特膜;光诱导相转变;核弹性散射;同步辐射粉末扩散;系统交叉动力学;瓦勒因子;中等数量的大环配体;FE-57 MOSSBAUER排放;C键形成;

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1. The spin-states and spin-transitions of mononuclear iron(II) complexes of nitrogen-donor ligands [J] . Halcrow MA Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2007,第14期

机译：氮供体配体的单核铁（II）配合物的自旋态和自旋转变
2. Iron(II) spin-transition complexes with dendritic ligands, part II [J] . Wei Y., Sonar P., Grunert M., European journal of inorganic chemistry . 2010,第25期

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The spin-states and spin-transitions of mononuclear iron(II) complexes of nitrogen-donor ligands

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