Solvent induced reversible change of magnetic properties in a Fe(II)-Fe(III) single chain magnet

Kaneko Y; Kajiwara T; Yamane H; Yamashita M

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Solvent induced reversible change of magnetic properties in a Fe(II)-Fe(III) single chain magnet

机译：Fe（II）-Fe（III）单链磁体中溶剂诱导的磁性能可逆变化

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A single chain magnet (SCM), catena-[Fe-II(ClO4)(2)(Fe-III(bpca)(2)})ClO4 (1) includes three nitromethane molecules per a Fe(II)-Fe(III) unit as crystallized solvent which occupy the pores surrounded by four chains. Compound I can release or reabsorb these MeNO2 molecules like "sponges" possessing the chain structure of 1, accompanied by a reversible changing of SCM behavior during this process. Compound I is the first nano-magnet which shows the solvent induced reversible change of magnetic properties. (c) 2006 Elsevier Ltd. All rights reserved.

机译：单链磁体（SCM）链-[Fe-II（ClO4）（2）（Fe-III（bpca）（2）}）ClO4（1）在每个Fe（II）-Fe（III）中包含三个硝基甲烷分子）单元为结晶溶剂，占据被四个链围绕的孔。化合物I可以释放或重新吸收这些MeNO2分子，例如具有1链结构的“海绵”，同时在此过程中伴随着SCM行为的可逆变化。化合物I是第一个显示出溶剂诱导的磁性能可逆变化的纳米磁体。（c）2006 Elsevier Ltd.保留所有权利。

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《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |2007年第11期|共5页
作者
Kaneko Y; Kajiwara T; Yamane H; Yamashita M;
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正文语种 eng
中图分类化学;
关键词
single chain magnet; solvent adsorption/desorption; crystal structure; POLE INVERSION; NANOWIRES;

机译：单链磁体;溶剂吸附/解吸;晶体结构;极点反演;纳米;

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1. Solvent induced reversible change of magnetic properties in a Fe(II)-Fe(III) single chain magnet [J] . Kaneko Y, Kajiwara T, Yamane H, Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2007,第9a11期

机译：Fe（II）-Fe（III）单链磁体中溶剂诱导的磁性能可逆变化
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Solvent induced reversible change of magnetic properties in a Fe(II)-Fe(III) single chain magnet

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