SYNTHESIS, CHARACTERIZATION AND SPECTROSCOPIC PROPERTIES OF [CU-I(ALKYLISOCYANIDE)(4)]BF4 COMPLEXES - X-RAY CRYSTAL STRUCTURES OF [CU(MIBI)(4)]BF4 AND [CU(CPI)(4)]BF4

Deicas B.; Kremer C.; Kremer E.; Mombru A.; Suescun L. Mariezcurrena R.; Gonzalez O.; Rey A.; Mallo L.; Leon A.; Gambino D.

首页> 外文期刊>Polyhedron: The International Journal for Inorganic and Organometallic Chemistry >SYNTHESIS, CHARACTERIZATION AND SPECTROSCOPIC PROPERTIES OF [CU-I(ALKYLISOCYANIDE)(4)]BF4 COMPLEXES - X-RAY CRYSTAL STRUCTURES OF [CU(MIBI)(4)]BF4 AND [CU(CPI)(4)]BF4

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SYNTHESIS, CHARACTERIZATION AND SPECTROSCOPIC PROPERTIES OF [CU-I(ALKYLISOCYANIDE)(4)]BF4 COMPLEXES - X-RAY CRYSTAL STRUCTURES OF [CU(MIBI)(4)]BF4 AND [CU(CPI)(4)]BF4

机译：[CU-I（烷基异氰酸酯）（4）] BF4复合物的合成，表征和光谱性质-[CU（MIBI）（4）] BF4和[CU（CPI）（4）] BF4的X射线晶体结构

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Alkylisocyanide complexes of copper(I) with formula [Cu(CNR)(4)]BF4 [where R = 2-methoxyisobutyl and 2-(carbomethoxy)-2-methylethyl] were synthesized by direct reaction of cuprous chloride with ligand. The stability of solid complexes and their aqueous solutions were tested by HPLC. Comparative studies were carried out on electronic, IR and H-1 NMR spectroscopy. Crystal structures of [Cu(MIBI)(4)]BF4 and [Cu(CPI)(4)]BF4 were determined from X-ray data and show a tetrahedral arrangement of ligands around the central copper atom in both compounds. (C) 1997 Elsevier Science Ltd. [References: 21]

机译：通过氯化亚铜与配体的直接反应，合成具有式[Cu（CNR）（4）] BF4 [其中R = 2-甲氧基异丁基和2-（羰甲氧基）-2-甲基乙基]的铜（I）烷基异氰化物配合物。固体配合物及其水溶液的稳定性通过HPLC测试。在电子，IR和H-1 NMR光谱上进行了比较研究。从X射线数据确定[Cu（MIBI）（4）] BF4和[Cu（CPI）（4）] BF4的晶体结构，并显示两种化合物中中心铜原子周围的配体的四面体排列。（C）1997 Elsevier Science Ltd. [参考：21]

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《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |1997年第14期|共7页
作者
Deicas B.; Kremer C.; Kremer E.; Mombru A.; Suescun L. Mariezcurrena R.; Gonzalez O.; Rey A.; Mallo L.; Leon A.; Gambino D.;
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正文语种 eng
中图分类化学;无机化学;
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Copper(i) complexes; Copper(i) alkylisocyanide complexes; Structure of cu(mibi)(4)bf4; Structure of cu(cpi)(4)bf4; Technetium;

机译：铜（i）配合物;铜（i）烷基异氰化物配合物;[cu（mibi）（4）] bf4的结构;[cu（cpi）（4）] bf4的结构;

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1. SYNTHESIS, CHARACTERIZATION AND SPECTROSCOPIC PROPERTIES OF [CU-I(ALKYLISOCYANIDE)(4)]BF4 COMPLEXES - X-RAY CRYSTAL STRUCTURES OF [CU(MIBI)(4)]BF4 AND [CU(CPI)(4)]BF4 [J] . Deicas B., Kremer C., Kremer E., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 1997,第14期

机译：[CU-I（烷基异氰酸酯）（4）] BF4复合物的合成，表征和光谱性质-[CU（MIBI）（4）] BF4和[CU（CPI）（4）] BF4的X射线晶体结构
2. THE PREPARATION AND CATALYTIC PROPERTIES OF COPPER(II) COMPLEXES DERIVED FROM A PYRAZOLE CONTAINING LIGAND - X-RAY CRYSTAL STRUCTURE OF [CU(PZMHP)(BF4)](BF4) [J] . Malachowski MR., Davidson MG., Driessen WL., Inorganica Chimica Acta . 1997,第1期

机译：含吡咯配体的铜（II）配合物的制备及其催化性能-[CU（PZMHP）（BF4）]（BF4）的X射线晶体结构
3. 3-(Diallylamino)propanenitrile ((C3H5)2NC2H4CN9 L) π-Complexes with Copper(I) Ionic Salts. Syntheses and Crystal Structures of Compounds [Cu(H~+L)ClO4]ClO4 · H2O, [Cu(H~+L)BF4]BF4 · H2O, and [Cu(H~+L)(H2O)]SiF6 · H2O [J] . M. Yu. Lukyanov, A. V. Pavlyuk, E. A. Goreshnik Russian Journal of Coordination Chemistry . 2012,第9期

机译：3-（二烯丙基氨基）丙腈（（C3H5）2NC2H4CN9 L）π-络合物与铜（I）离子盐。 [Cu（H〜+ L）ClO4] ClO4·H2O，[Cu（H〜+ L）BF4] BF4·H2O和[Cu（H〜+ L）（H2O）] SiF6·H2O的合成及晶体结构
4. Synthesis, Single Crystal Structure, and Magnetic Properties of 3-D Cu(NITpPy)2Cu(CN)3.2CH3OH.2H2O Complexes [C] . I W Dasna, S Golhen, L Ouahab International Conference on Advanced Materials Science and Technology . 2017

机译：3-D Cu（Nitppy）2 Cu（CN）3 .2CH3OH2H2O复合物的合成，单晶结构和磁性性能
5. Phase-selective synthesis of Tl-Ba-Ca-Cu-O thin films and multilayer structures by metal-organic chemical vapor deposition. Process optimization, phase evolution, electrical characterizations, and microstructural developments. [D] . McNeely, Richard Joseph. 1999

机译：通过金属有机化学气相沉积相选择合成Tl-Ba-Ca-Cu-O薄膜和多层结构。工艺优化，相变，电学表征和微结构发展。
6. Synthesis Characterization and Bioactivity of Schiff Bases and Their Cd2+ Zn2+ Cu2+ and Ni2+ Complexes Derived from Chloroacetophenone Isomers with S-Benzyldithiocarbazate and the X-Ray Crystal Structure of S-Benzyl-β-N-(4-chlorophenyl)methylenedithiocarbazate [O] . Mohammed Khaled bin Break, M. Ibrahim M. Tahir, Karen A. Crouse, 2013

机译：席尔苯乙酮异构体与S-苄基二硫代氨基甲酸酯的席夫碱及其Cd2 +Zn2 +Cu2 +和Ni2 +配合物的合成表征和生物活性以及S-苄基-β-N-（4-氯苯基）亚甲基二硫代氨基甲酸酯的X射线晶体结构
7. Copper(I) complexes with 5-(allylthio)-1H-tetrazoles: synthesis and crystal structure of Cu2(C10H10N4S)2(H2O)2(BF4)2 and Cu2(C10H9ClN4S)2(H2O)2(BF4)2·C2H5OH π-compounds (C10H10N4S and C10H9ClN4S - 5-(allylthio)-1-phenyl- and 5-(allylthio)-1-(4-chlorophenyl)-1H-tetrazole) [O] . Yuriy SLYVKA, Nazariy POKHODYLO, Roman SAVKA, 2010

机译：铜（I）配合物，具有5-（烯丙基硫基）-1H-四唑：Cu 2（C10H10N4S）2（H 2 O）2（BF4）2和Cu 2（C10H9ClN 4）2（H2O）2的合成和晶体结构（BF4 ）2·C 2 H 5 OHπ-化合物（C10H10N4S和C10H9CLN4S - 5-（烯丙基硫基）-1-苯基 - 和5-（烯丙基）-1-（4-氯苯基）-1H-四唑）
8. Correlation of polycrystalline Cu(In,Ga)Se(sub 2) device efficiency with homojunction depth and interfacial structure: X-ray photoemission and positron annihilation spectroscopic characterization [R] . Nelson, A. J., Sobol, P. E., Gabor, A. M., 1994

机译：多晶Cu（In，Ga）se（sub 2）器件效率与同质结深度和界面结构的相关性：X射线光电发射和正电子湮没光谱表征

SYNTHESIS, CHARACTERIZATION AND SPECTROSCOPIC PROPERTIES OF [CU-I(ALKYLISOCYANIDE)(4)]BF4 COMPLEXES - X-RAY CRYSTAL STRUCTURES OF [CU(MIBI)(4)]BF4 AND [CU(CPI)(4)]BF4

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