Bismuth (III) coordination to cyclen and cyclam bearing four appended groups

Jean-Francois Morfin; Raphael Tripier; Michel Le Baccon; Henri Handel

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Bismuth (III) coordination to cyclen and cyclam bearing four appended groups

机译：铋（III）与Cyclon和Cyclam配合四个附加组

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The synthesis of new cyclam and cyclen derivatives (respectively L1 and L2), able to efficiently coordinate to Bi(III) are presented here. The two ligands bearing two different pendant arms (two-pycolyl and two (2-(2-hydroxyethoxy)ethyl)-2-aminoacetamide in trans position) were synthesized in the aim to obtain stable and water soluble complexes. The thermodynamic and kinetic of the formation of the corresponding complexes in aqueous solution were studied by means of NMR and potentiometric investigations. The fast kinetic of complexation and the high stability of the complexes are encouraging for further application with the alpha-emitting 213Bi isotope.

机译：这里介绍了能够有效配位到Bi（III）的新的cyclam和cycln衍生物（分别为L1和L2）的合成。为了获得稳定且水溶性的络合物，合成了带有两个不同悬垂臂的两个配体（两个缩水甘油基和两个（反式（2-（2-羟基乙氧基）乙基）-2-氨基乙酰胺）。通过NMR和电位研究研究了在水溶液中形成相应配合物的热力学和动力学。配合物的快速动力学和配合物的高稳定性令人鼓舞，可进一步用于发射α的213Bi同位素。

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来源
《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |2009年第17期|共8页
作者
Jean-Francois Morfin; Raphael Tripier; Michel Le Baccon; Henri Handel;
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正文语种 eng
中图分类无机化学;
关键词
Bismuth; Cyclen; Cyclam; Complexation;

机译：铋;Cyclen;Cyclam;复杂;

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1. Bismuth (III) coordination to cyclen and cyclam bearing four appended groups [J] . Jean-Francois Morfin, Raphael Tripier, Michel Le Baccon, Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2009,第17期

机译：铋（III）与Cyclon和Cyclam配合四个附加组
2. Syntheses and characterization of a new nano-structured bismuth(III) bromide coordination polymer; new precursor for preparation of bismuth(III) bromide and bismuth(III) oxide nanostructures [J] . NILOFAR SOLTANZADEH, ALI MORSALI Journal of Coordination Chemistry . 2009,第17期

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3. Syntheses and characterization of a new nano-structured bismuth(III) bromide coordination polymer; new precursor for preparation of bismuth(III) bromide and bismuth(III) oxide nanostructures [J] . Nilofar Soltanzadeha amp, Ali Morsalia* Journal of Co-ordination Chemistry . 2009,第17期

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4. Cyclen を基盤とする八座配位子を用いたLn(III)錯体の合成と磁気特性 [C] . 硲有沙, 入佐充音, 工藤真弓日本化学会春季年会 . 2020

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5. Wurster's Azacrowns: Synthesis and properties of Wurster's Cyclam derivatives and their coordination chemistry with group 12 metal cations. [D] . Lund, Benjamin R. 2008

机译：Wurster的Azacrowns：Wurster的Cyclam衍生物的合成，性质及其与第12组金属阳离子的配位化学。
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Bismuth (III) coordination to cyclen and cyclam bearing four appended groups

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