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Pulweryzacja materialow polimerowych mtoda wytlacznaia scinajacego w stanie stalym

机译:通过固体剪切挤出对聚合物材料进行粉碎

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摘要

A review with 36 refs. covering techniques and equipment used to shear-extrude solid polymeric materials. the technique involves the application of normal and shear forces in combination with high pressure and suitable modifications of polymer temperature, viz., first preheating to plastify and to homogenize the polymer and subsequently cooling to bring the polymer below the solidification point. Two technical modifications are described, involving comminution of the polymer carried out either inside or outside of the extruder's plastifying system; modified extruder designs are shown. The technique enables homogeneous fine (particle size even <100 #mu#m) polymer powders to be preprared. Incompatible polymers, which phase-separate and cannot be processed by conventional melt extrusion, can be homogenized and comminuted (and thereby later recycled) in a continuous way and also copulverized to yield blends.
机译:有36个裁判的评论。覆盖技术和设备用于剪切挤出固体聚合物材料。该技术涉及施加法向力和剪切力,并结合高压和适当改变聚合物温度,即首先预热以使聚合物塑化和均化,然后冷却以使聚合物低于凝固点。描述了两种技术改进,包括粉碎在挤出机塑化系统内部或外部进行的聚合物。显示了改进的挤出机设计。该技术可以制备均质的精细(甚至小于100#μ#m的粒径)聚合物粉末。相分离且不能通过常规熔融挤出加工的不相容聚合物可以连续方式进行均质和粉碎(然后再循环使用),也可以进行共粉化以生成共混物。

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