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首页> 外文期刊>Polyhedron: The International Journal for Inorganic and Organometallic Chemistry >Frustration effects in antiferromagnetic molecules: The cuboctahedron
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Frustration effects in antiferromagnetic molecules: The cuboctahedron

机译:反铁磁分子的挫折效应:立方八面体

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摘要

Frustration of magnetic systems which is caused by competing interactions is the driving force of several unusual phenomena such as plateaus and jumps of the magnetization curve as well as of unusual energy spectra with for instance many singlet levels below the first triplet state. The antiferromagnetic cuboctahedron can serve as a paradigmatic example of certain frustrated anti ferromagnets. In addition it has the advantage that its complete energy spectrum can be obtained up to individual spin quantum numbers of s=3/2 (16777216 states).
机译:由竞争相互作用引起的磁系统的失灵是几种异常现象的驱动力,例如磁化曲线的平稳和跳跃,以及例如在第一三重态以下的许多单重态能级的异常能谱。反铁磁立方八面体可以作为某些受挫的反铁磁体的范例。此外,它的优点是,可以得到高达s = 3/2的自旋量子数(16777216状态)的完整能谱。

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