Synthesis and characterization of rhenium carbonyltrifluoroacetate complexes with phosphites, phosphonites and phosphinites

Bolano S; Bravo J; Castro J; Garcia-Fontan S; Rodriguez MC

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Synthesis and characterization of rhenium carbonyltrifluoroacetate complexes with phosphites, phosphonites and phosphinites

机译：羰基三氟乙酸rh与亚磷酸酯，亚膦酸酯和次膦酸酯的配合物的合成与表征

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The rhenium(I) complexes [Re(O2CCF3)CO)(3)(L)] (1) and [Re(O2CCF3)(CO)(2)LL'] (L = Ph2POCH2CH2OPPh2: L' = PPhn(OR)(3-n); R = Me, Et; n = 0-2) (2a-f) have been synthesised by the reaction of the parent bromo derivatives with AgO2CCF3. These compounds have been characterized by microanalysis, IR, NMR, mass spectrometry and, in the cases of 1 and 2a, by X-ray diffraction. The metal is in a distorted octahedral environment with the trifluoroacetate ligand acting in a monodentate manner.

机译：（（I）配合物[Re（O2CCF3）CO）（3）（L）]（1）和[Re（O2CCF3）（CO）（2）LL']（L = Ph2POCH2CH2OPPh2：L'= PPhn（OR）（3-n）; R ＝ Me，Et; n ＝ 0-2）（2a-f）已经通过母体溴衍生物与AgO 2 CCF 3的反应合成。这些化合物的特征在于微分析，IR，NMR，质谱，在1a和2a的情况下，通过X射线衍射表征。金属处于扭曲的八面体环境中，三氟乙酸酯配体以单齿方式起作用。

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《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |2009年第12期|共5页
作者
Bolano S; Bravo J; Castro J; Garcia-Fontan S; Rodriguez MC;
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正文语种 eng
中图分类无机化学;
关键词
Carbonyls; Rhenium; Phosphites; Phosphonites; Phosphinites;

机译：羰基;R;亚磷酸酯;亚膦酸酯;亚磷酸酯;

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1. Synthesis and characterization of rhenium carbonyltrifluoroacetate complexes with phosphites, phosphonites and phosphinites [J] . Bolano S, Bravo J, Castro J, Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2009,第12期

机译：羰基三氟乙酸rh与亚磷酸酯，亚膦酸酯和次膦酸酯的配合物的合成与表征
2. Hydride and dihydrogen dicarbonylrhenium(I) complexes with phosphites, phosphonites and phosphinites [J] . Bolano Sandra, Bravo Jorge, Fernandez-Garcia Flor, Journal of Organometallic Chemistry . 2009,第18期

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3. Synthesis and characterization of iron complexes based on bis-phosphinite PONOP and bis-phosphite PONOP pincer ligands [J] . DeRieux Wing-Sy W., Wong Aaron, Schrodi Yann Journal of Organometallic Chemistry . 2014,第Null期

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6. Synthesis and Characterization of Iron Complexes based on Bis-Phosphinite PONOP and Bis-Phosphite PONOP Pincer Ligands [O] . Wing-Sy W. DeRieux, Aaron Wong, Yann Schrodi -1

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Synthesis and characterization of rhenium carbonyltrifluoroacetate complexes with phosphites, phosphonites and phosphinites

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