Crystal packing in a solvent-free or chloroform-solvated dinuclear platinum(III) organometallic complex

Romero M.J.; Rodríguez A.; Fernández A.; López-Torres M.; Vázquez-García D.; Vila J.M.; Fernández J.J.

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Crystal packing in a solvent-free or chloroform-solvated dinuclear platinum(III) organometallic complex

机译：无溶剂或氯仿溶剂的双核铂（III）有机金属配合物的晶体堆积

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The synthesis and crystal structure determination of the dinuclear organometallic platinum(III) complex [Pt(2-phenylpyridine)(2-mercaptothiazoline) (Cl)]_2 and its solvate [Pt(2-phenylpyridine)(2-mercaptothiazoline) (Cl)]_2·3CHCl~3 have been performed. Both crystals present a layered structure in which the molecules of the complex are held together by weak intermolecular interactions. In the solvated crystal, the chloroform molecules are arranged in extended 2D planar layers between the molecular layers.

机译：双核有机金属铂（III）配合物[Pt（2-苯基吡啶）（2-巯基噻唑啉）（Cl）] _ 2及其溶剂化物[Pt（2-苯基吡啶）（2-巯基噻唑啉）（Cl）的合成和晶体结构测定已进行] _2·3CHCl〜3。两种晶体都呈现出层状结构，其中复合物的分子通过弱的分子间相互作用而保持在一起。在溶剂化的晶体中，氯仿分子排列在分子层之间的扩展二维平面层中。

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《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |2011年第15期|共7页
作者
Romero M.J.; Rodríguez A.; Fernández A.; López-Torres M.; Vázquez-García D.; Vila J.M.; Fernández J.J.;
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正文语种 eng
中图分类无机化学;
关键词
Crystal packing; Cyclometallation; Platinum; X-ray structure;

机译：晶体堆积环金属化铂X射线结构;

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1. Crystal packing in a solvent-free or chloroform-solvated dinuclear platinum(III) organometallic complex [J] . Romero M.J., Rodríguez A., Fernández A., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2011,第15期

机译：无溶剂或氯仿溶剂的双核铂（III）有机金属配合物的晶体堆积
2. Organometallic chemistry of platinum-blue derived platinum~Ⅲ dinuclear complexes [J] . Kazuko Matsumoto, Masahiko Ochiai Coordination chemistry reviews . 2002,第1a2期

机译：铂蓝衍生的铂〜Ⅲ双核配合物的有机金属化学
3. Oxidation of Organoplatinum(II) by Coordinated Dimethylsulfoxide: Metal-Metal Bonded, Dinuclear, Liquid-Crystalline Complexes of Platinum(III) [J] . Amedeo Santera, Marcin Wegrzyn, Adrian C. Whitwood, Journal of the American Chemical Society . 2010,第31期

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Crystal packing in a solvent-free or chloroform-solvated dinuclear platinum(III) organometallic complex

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