Ruthenium(II) complexes with quinoline carboxylate as a co-ligand

Ma?ecki J.G.; Maroń A.; Gryca I.; Mori A.; Suzuki T.

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Ruthenium(II) complexes with quinoline carboxylate as a co-ligand

机译：钌（II）与喹啉羧酸盐作为共配体的配合物

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Ruthenium(II) complexes with the general formulas [Ru(H/Cl)(CO)(PPh _3)_2(L)] and cis/trans-[Ru(PPh_3)_ 2(-L)_2] (L = isoquinoline-1-carboxylate or quinoline-2-carboxylate) were synthesized and characterized by IR, ~1H, ~(13)C and ~(31)P NMR, UV-Vis spectroscopy and X-ray crystallography. The experimental studies were completed by quantum chemical calculations, which were used to describe the nature of the interactions between the ligands and the central ion, and the orbital compositions in the frontier electronic structures. Based on a molecular orbital scheme, the calculated results allowed the interpretation of the UV-Vis spectra obtained at an experimental level. The luminescence properties of the complexes were determined.

机译：具有通式[Ru（H / Cl）（CO）（PPh _3）_2（L）]和顺/反-[Ru（PPh_3）_2 2（-L）_2]的钌（II）配合物（L =异喹啉合成了-1-羧酸盐或喹啉-2-羧酸盐，并通过IR，〜1H，〜（13）C和〜（31）P NMR，UV-Vis光谱和X射线晶体学进行了表征。通过量子化学计算完成了实验研究，量子化学计算用于描述配体与中心离子之间相互作用的性质以及前沿电子结构中的轨道组成。基于分子轨道方案，计算结果可以解释在实验水平获得的UV-Vis光谱。测定配合物的发光性质。

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《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |2013年第null期|共15页
作者
Ma?ecki J.G.; Maroń A.; Gryca I.; Mori A.; Suzuki T.;
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正文语种 eng
中图分类 54.4;
关键词
Absorption and emission electronic spectra; DFT; Isoquinoline carboxylate; Quinoline carboxylate; Ruthenium complexes;

机译：吸收和发射电子光谱;DFT;异喹啉羧酸盐;喹啉羧酸盐;钌配合物;

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1. Ruthenium(II) complexes with quinoline carboxylate as a co-ligand [J] . Ma?ecki J.G., Maroń A., Gryca I., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2013,第Null期

机译：钌（II）与喹啉羧酸盐作为共配体的配合物
2. Benign synthesis of the unsymmetrical ligand N-(8-quinolyl)quinoline-2-carboxamide (Hqcq) and the varied crystal chemistry of its Cu(II), Zn(II), and Cd(II) complexes bearing acetato and aqua co-ligands [J] . Soraia Meghdadi, Mehdi Amirnasr, S. B. Hoda Moein Sadat Monatshefte fur Chemie . 2014,第10期

机译：非对称配体N-（8-喹啉基）喹啉-2-羧酰胺（Hqcq）的良性合成及其带有acetato和aqua co-的Cu（II），Zn（II）和Cd（II）配合物的不同晶体化学配体
3. Ruthenium(II/III)-bipyridine complexes with four-membered sulphur donor co-ligands: synthesis, metal valence preference, spectroscopic and electron-transfer properties [J] . Kulkarni SS., Munshi P., Lahiri GK., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 1998,第25a26期

机译：具有四元硫供体共配体的钌（II / III）-联吡啶配合物：合成，金属化合价，光谱和电子转移性质
4. Thiaallyl Complexes of Ruthenium(II) and Iron( II) [C] . Yusuke Sunada, Tsubasa Hatanaka, Kazuyuki Tatsumi Symposium on Organometallic Chemistry . 2004

机译：钌（II）和铁（II）的硫化物复合物
5. Photochemistry of group 8 metal complexes of type [M(bpy)2 cyanogen] (M = iron, ruthenium). Photosynthesis of heteroleptic iron(II) compounds and photoionization of ruthenium(II) compounds, or, Photoassisted synthesis of heteroleptic iron(II) compounds and photoionization of ruthenium(II) complexes. [D] . Turner, David Benjamin. 2009

机译：[M（bpy）2氰基]类型的第8组金属配合物的光化学（M =铁，钌）。杂合铁（II）化合物的光合作用和钌（II）化合物的光电离，或者杂合铁（II）化合物的光辅助合成和钌（II）配合物的光电离。
6. Synthesis Characterization Cytotoxic Activity and Interactions with CT-DNA and BSA of Cationic Ruthenium(II) Complexes Containing Dppm and Quinoline Carboxylates [O] . Edinaldo N. da Silva, Paulo A. B. da Silva, Angélica E. Graminha, 2017

机译：含Dppm和喹啉羧酸盐的阳离子钌（II）配合物的合成表征细胞毒活性以及与CT-DNA和BSA的相互作用
7. Synthesis, spectral, dna binding and cleavage properties of ruthenium(II) Schiff base complexes containing PPh3/AsPh3 as co-ligands [O] . Sathiyaraj Subbaiyan, Ayyannan Ganesan, Jayabalakrishnan Chinnasamy 2014

机译：含有pph3 / asph3作为共配体的钌（II）席夫碱配合物的合成，光谱，dna结合和解理性质
8. Factors Affecting Chelation of Carboxylates to cis-Diaqua Co(III) Complexes:Implications on the Reactivity of the Metal Complexes for Hydrolyzing Esters, Amides, Nitriles, and Phosphates [R] . Connolly, J. A., Kim, J. H., Banaszczyk, M., 1995

机译：影响羧酸盐与顺式 - 二型Co（III）配合物螯合作用的因素：金属配合物对水解酯，酰胺，腈和磷酸盐的反应性的影响

Ruthenium(II) complexes with quinoline carboxylate as a co-ligand

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