Functionalized bipyridyl rhodium complex capable of electrode attachment for regeneration of NADH

Sivanesan D.; Yoon S.

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Functionalized bipyridyl rhodium complex capable of electrode attachment for regeneration of NADH

机译：能够附着电极以再生NADH的功能化联吡啶铑配合物

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摘要

A Rh(III) complex having a functionalized bpy-OH ligand that is potentially linkable to electrode surfaces was synthesized and fully characterized. The hydrido complex, which could be generated either electrochemically by cathodic reduction of the [η~5-Cp~*Rh(bpy-OH)Cl]Cl complex at -771 mV (versus Ag/AgCl) or chemically with formate, transformed NAD ~+ efficiently into NADH with a TOF = 710 at 60 C.

机译：合成并完全表征了具有潜在地可连接至电极表面的具有官能化bpy-OH配体的Rh（III）配合物。氢化物络合物，可通过在-771 mV（相对于Ag / AgCl）上通过阴极还原[η〜5-Cp〜* Rh（bpy-OH）Cl] Cl络合物的电化学方法生成，或与甲酸盐化学反应生成的NAD 〜+在60°C下有效转化为NADH，TOF = 710。

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《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |2013年第null期|共5页
作者
Sivanesan D.; Yoon S.;
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正文语种 eng
中图分类无机化学;
关键词
Chemical method; Crystal structure; Indirect electrochemical method; NADH regeneration;

机译：化学法;晶体结构;间接电化学法;NADH再生;

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专利

1. Functionalized bipyridyl rhodium complex capable of electrode attachment for regeneration of NADH [J] . Sivanesan D., Yoon S. Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2013,第Null期

机译：能够附着电极以再生NADH的功能化联吡啶铑配合物
2. Factors affecting the electrochemical regeneration of NADH by (2,2'-bipyridyl) (pentamethylcyclopentadienyl)-rhodium complexes: Impact on their immobilization onto electrode surfaces [J] . Walcarius A., Nasraoui R., Wang Z., Bioelectrochemistry . 2011,第1期

机译：（2,2'-联吡啶）（五甲基环戊二烯基）-铑配合物影响NADH电化学再生的因素：对将其固定到电极表面的影响
3. Efficient electrochemical regeneration of nicotinamide cofactors using a cyclopentadienyl-rhodium complex on functionalized indium tin oxide electrodes [J] . Soojin Kim, Ga Ye Lee, Jungha Lee, Electrochimica Acta . 2013,第Null期

机译：在功能化的铟锡氧化物电极上使用环戊二烯基-铑配合物对烟酰胺辅因子进行高效电化学再生
4. Bifunctional Carbon Adsorbent Capable ofAdsorption and Self-regeneration [C] . Chang Hun Yun, Gyu Hwan Oh, Chong Rae Park Carbon 2005 . 2005

机译：具有吸附和自我再生功能的双功能碳吸附剂
5. Metal-Rhodium Bonded Paddlewheel Complexes (Metal = Rhodium or Bismuth): Consequences of Exchanging Rhodium for Bismuth on their Structure and Reactivity Related to C-H Functionalization Catalysis. [D] . Sunderland, Travis Lee. 2016

机译：金属-铑键合的桨叶配合物（金属=铑或铋）：铑与铋交换在结构和与C-H功能化催化相关的反应性上的后果。
6. Robust Binding of Disulfide-Substituted Rhenium Bipyridyl Complexes for CO2 Reduction on Gold Electrodes [O] . Mauricio Cattaneo, Facheng Guo, H. Ray Kelly, 2020

机译：二硫键取代的Bi联吡啶配合物在金电极上的牢固结合可减少CO2的生成
7. Water-Soluble Phenanthroline Complexes of Rhodium, Iridium and Ruthenium for the Regeneration of NADH in the Enzymatic Reduction of Ketones [O] . Canivet, Jérôme, Süss-Fink, Georg, Štěpnička, Petr 2009

机译：铑，铱和钌的水溶性邻菲咯啉配合物用于酮酶还原中NADH的再生

Functionalized bipyridyl rhodium complex capable of electrode attachment for regeneration of NADH

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