STANDARD ENTHALPY OF FORMATION OF DICHLOROIODINE(III) TETRACHLOROALUMINIUM(III), [ICL2(+)][ALCL4(-)] AND THE THERMOCHEMISTRY AND ENERGETICS OF THE GASEOUS DICHLOROIODINE(III) CATION, [ICL2(+)]

Jenkins HDB.; Finch A.; Gates PN.; Derakhshan BM.

首页> 外文期刊>Polyhedron: The International Journal for Inorganic and Organometallic Chemistry >STANDARD ENTHALPY OF FORMATION OF DICHLOROIODINE(III) TETRACHLOROALUMINIUM(III), [ICL2(+)][ALCL4(-)] AND THE THERMOCHEMISTRY AND ENERGETICS OF THE GASEOUS DICHLOROIODINE(III) CATION, [ICL2(+)]

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STANDARD ENTHALPY OF FORMATION OF DICHLOROIODINE(III) TETRACHLOROALUMINIUM(III), [ICL2(+)][ALCL4(-)] AND THE THERMOCHEMISTRY AND ENERGETICS OF THE GASEOUS DICHLOROIODINE(III) CATION, [ICL2(+)]

机译：二氯次古丁（III），四氯化铝（III），[ICL2（+）] [ALCL4（-）]形成的标准焓和气态二氯次古丁（III）阳离子[ICL2（+）]的热化学和能量

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The experimental determination of the standard enthalpy of formation of the crystalline salt [ICI2+][AlCl4-], is reported to be Delta(f)H(0)(IAlCl6,c)/kJ mol(-1) = -836.6 +/- 6.2 along with the total lattice potential energy, U-POT(IAlCl6)/kJ mol(-1), calculated to be 562.5 +/- 5.0 using the program LATEN. The standard enthalpy of formation of the [ICI2+] cation, Delta(f)H(0) ([ICI2+],g)/kJ mol(-1) is found to be 926.9 +/- 9.0. The electron attachment enthalpies for the ICI2 (g) and [ICI2+] (g) species, are in kJ mol(-1) : 533.2 and -999, respectively. (C) 1997 Elsevier Science Ltd. [References: 26]

机译：据报道，晶体盐[ICI2 +] [AlCl4-]形成标准焓的实验测定为Delta（f）H（0）（IAlCl6，c）/ kJ mol（-1）= -836.6 + / -6.2连同总晶格势能U-POT（IAlCl6）/ kJ mol（-1），使用程序LATEN计算得出为562.5 +/- 5.0。发现[ICI2 +]阳离子形成的标准焓Δ（f）H（0）（[ICI2 +]，g）/ kJ mol（-1）为926.9 +/- 9.0。 ICI2（g）和[ICI2 +]（g）物种的电子附着焓分别为kJ mol（-1）：533.2和-999。（C）1997 Elsevier Science Ltd. [参考：26]

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《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |1997年第20期|共5页
作者
Jenkins HDB.; Finch A.; Gates PN.; Derakhshan BM.;
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正文语种 eng
中图分类化学;无机化学;
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Enthalpy of formation; Lattice energy; Laten; Thermochemistry; icl2+; Ions;

机译：形成焓;晶格能;拉滕;热化学;[icl2 +];离子;

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1. STANDARD ENTHALPY OF FORMATION OF DICHLOROIODINE(III) TETRACHLOROALUMINIUM(III), [ICL2(+)][ALCL4(-)] AND THE THERMOCHEMISTRY AND ENERGETICS OF THE GASEOUS DICHLOROIODINE(III) CATION, [ICL2(+)] [J] . Jenkins HDB., Finch A., Gates PN., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 1997,第20期

机译：二氯次古丁（III），四氯化铝（III），[ICL2（+）] [ALCL4（-）]形成的标准焓和气态二氯次古丁（III）阳离子[ICL2（+）]的热化学和能量
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机译：铀化合物的热化学：XVI，量热法测定298.15 K的标准摩尔生成焓，低温热容和UO sub 2（OH）sub 2 /中心DOT / H sub 2 O的高温焓增量（ schoepite

STANDARD ENTHALPY OF FORMATION OF DICHLOROIODINE(III) TETRACHLOROALUMINIUM(III), [ICL2(+)][ALCL4(-)] AND THE THERMOCHEMISTRY AND ENERGETICS OF THE GASEOUS DICHLOROIODINE(III) CATION, [ICL2(+)]

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