Synthesis of intermediate sitting-atop complexes (i-SAT) from the reaction between free base meso-tetraarylporphyrins and phosphorus(III) chloride in solvent free media

Dehghani H; Shaterian M

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Synthesis of intermediate sitting-atop complexes (i-SAT) from the reaction between free base meso-tetraarylporphyrins and phosphorus(III) chloride in solvent free media

机译：在无溶剂介质中，由游离碱的内消旋四芳基卟啉与氯化磷（III）之间的反应合成中间坐位复合物（i-SAT）

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The reaction of meso-tetraarylporphyrins (H(2)tap) with phosphorus(III) chloride has been studied in the solid state. The reaction products are intermediate sitting-atop (i-SAT) complexes in which two pyrrole-nine nitrogen atoms of the porphyrins act as electron donors to the phosphorus(III) atoms and two protons on the pyrrole nitrogen atoms remain. These new complexes have been characterized by (H-1, P-31, C-13) NMR, FT-IR and UV-Vis spectroscopy, elemental analysis and electrical conductometry. (C) 2008 Published by Elsevier Ltd.

机译：介观四芳基卟啉（H（2）TAP）与氯化磷（III）的固态反应已进行了研究。反应产物是中间坐位（i-SAT）络合物，其中卟啉的两个吡咯-九个氮原子充当磷（III）原子的电子供体，并且在吡咯氮原子上保留两个质子。这些新的配合物已通过（H-1，P-31，C-13）NMR，FT-IR和UV-Vis光谱，元素分析和电导法表征。（C）2008由Elsevier Ltd.发布

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《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |2008年第15期|共4页
作者
Dehghani H; Shaterian M;
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正文语种 eng
中图分类化学;
关键词
Intermediate sitting-atop i-SAT; Porphyrin; Phosphorus(III) chloride; Deformation; MOLECULAR COMPLEXATION; TETRAPHENYLPORPHYRINS; PORPHYRINS; COPPER(II); SPECTRA; SYSTEMS; METAL;

机译：中间坐位i-SAT;卟啉;氯化磷（III）;变形;分子络合物;四苯并卟啉;卟啉;铜（II）;光谱;体系;金属;

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1. Synthesis of intermediate sitting-atop complexes (i-SAT) from the reaction between free base meso-tetraarylporphyrins and phosphorus(III) chloride in solvent free media [J] . Dehghani H, Shaterian M Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2008,第15期

机译：在无溶剂介质中，由游离碱的内消旋四芳基卟啉与氯化磷（III）之间的反应合成中间坐位复合物（i-SAT）
2. Synthesis and characterization of intermediate sitting-atop (i-SAT) complexes of free base meso-tetraarylporphyrins and tin(IV) chloride [J] . Dehghani H, Babaahmadi M Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2008,第13期

机译：游离内消旋四芳基卟啉与氯化锡（IV）的中间坐立（i-SAT）配合物的合成与表征
3. Synthesis, characterization and the thermodynamic study of intermediate sitting-atop (i-SAT) complexes of free base meso-tetraarylporphyrins with InC1_3 [J] . Hossein Dehghani, Maryam Bordbar, Mojtaba Mojiri-Foroushani, Inorganica Chimica Acta . 2009,第5期

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Synthesis of intermediate sitting-atop complexes (i-SAT) from the reaction between free base meso-tetraarylporphyrins and phosphorus(III) chloride in solvent free media

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