A homoleptic SPS-based complex and a double-cubane-type sulfur cluster of an actinide element

Arliguie T; Thuery P; Le Floch P; Mezailles N; Ephritikhine M

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A homoleptic SPS-based complex and a double-cubane-type sulfur cluster of an actinide element

机译：基于均一的SPS的络合物和act系元素的双古巴型硫簇

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摘要

Treatment of UI3(THF)(4) with [M(Et2O)][SPSMe] (M = Li, K; [SPSMe] = 1-methyl-2,6-bis(diphenylphosphine sulfide)-3,5-diphenylphosphinine anion) gave the cationic tris SPS complex [U(SPSMe)(3)]I (1). Similar reaction of U(BH4)(3)(THF)(3) and [M(Et2O)][SPSMe] afforded, in addition to the [U(SPS)(3)](+) cation, crystals of the sulfido complex [U{(mu(3)-S)(4)U-3(SPSMe)(3)(BH4)(3)}(2)] (2). The metal environment in 1 is a tricapped trigonal prism and the core of the heptanuclear cluster 2 is a corner-shared double-cubane.

机译：用[M（Et2O）] [SPSMe]（M = Li，K; [SPSMe] = 1-甲基-2,6-双（二苯基膦硫醚）-3,5-二苯基次膦阴离子）处理UI3（THF）（4））得到阳离子tris SPS络合物[U（SPSMe）（3）] I（1）。除了[U（SPS）（3）]（+）阳离子外，U（BH4）（3）（THF）（3）和[M（Et2O）] [SPSMe]的类似反应得到了硫化物的晶体复杂的[U {（mu（3）-S）（4）U-3（SPSMe）（3）（BH4）（3）}（2）]（2）。 1中的金属环境是一个三棱柱三角棱镜，而七核簇2的核心是一个共享角的双库伦。

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来源
《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |2009年第8期|共5页
作者
Arliguie T; Thuery P; Le Floch P; Mezailles N; Ephritikhine M;
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正文语种 eng
中图分类无机化学;
关键词
Uranium; SPS ligand; Sulfide; Cluster; Cubane; X-ray crystal structure;

机译：铀;SPS配体;硫化物;簇;立方烷;X射线晶体结构;

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1. A homoleptic SPS-based complex and a double-cubane-type sulfur cluster of an actinide element [J] . Arliguie T, Thuery P, Le Floch P, Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2009,第8期

机译：基于均一的SPS的络合物和act系元素的双古巴型硫簇
2. Synthesis and properties of homoleptic 2,2'-bipyridyl complexes of rare-earth elements. Crystal and molecular structures of the complexes Ln(N_(2)C_(10)H_8)_4 (Ln = Sm, Eu, Yb, or Lu) and the ionic complex [Lu(N_2C_(10)H_8)_4][Li(THF)_4] [J] . I. L. Fedushkin, T. V. Petrovskaya, F. Girgsdies, Russian Chemical Bulletin . 2000,第11期

机译：稀土元素均2,2'-联吡啶基配合物的合成和性质。配合物Ln（N_（2）C_（10）H_8）_4（Ln = Sm，Eu，Yb或Lu）和离子配合物[Lu（N_2C_（10）H_8）_4] [Li（ THF）_4]
3. In pursuit of homoleptic actinide alkyl complexes [J] . Seaman L.A., Walensky J.R., Wu G., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2013,第7期

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4. Role of complex formation with humic substances in the redistribution of trivalent rare earth elements and actinides [C] . Y.Takahashi, Y.Minai Water-Rock Interaction . 2001

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5. Defining the Role of the Cytosolic Iron-Sulfur Cluster Assembly Targeting Complex in Identification of Iron-Sulfur Cluster Proteins [D] . Vo, Amanda Thuy Van. 2018

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6. Assessing crystal field and magnetic interactions in diuranium-μ-chalcogenide triamidoamine complexes with UIV–E–UIV cores (E = S Se Te): implications for determining the presence or absence of actinide–actinide magnetic exchange [O] . Benedict M. Gardner, David M. King, Floriana Tuna, 2017

机译：评估具有UIV–E–UIV核（E = SSeTe）的铀-μ-硫族化物三酰胺胺配合物（E = SSeTe）中的晶体场和磁相互作用：确定是否存在act系元素-act系元素磁性交换的含义
7. Back Cover: Coordination Chemistry of Homoleptic Actinide(IV)-Thiocyanate Complexes (Chem. Eur. J. 44/2015) [O] . Tyler J. Carter, Richard E. Wilson 2015

机译：返回封面：聚类猕猴桃（IV）的协调化学 - 硫氰酸酯配合物（Chem.EUR。J. 44/2015）

A homoleptic SPS-based complex and a double-cubane-type sulfur cluster of an actinide element

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