The molecular structure of a 2-aryl-1,3,2-dioxaphospholane and its coordination behaviour towards platinum(II) species; molecular structures of four platinum(II) complexes

Dillon KB; Goeta AE; Monks PK; Shepherd HJ

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The molecular structure of a 2-aryl-1,3,2-dioxaphospholane and its coordination behaviour towards platinum(II) species; molecular structures of four platinum(II) complexes

机译：2-芳基-1,3,2-二氧杂膦烷的分子结构及其对铂（II）物种的配位行为;四种铂（II）配合物的分子结构

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The molecular structure of the 2-aryl-1,3,2-dioxaphospholane, 2,6-(CF3)(2)-C6H3-P(OCH2)(2) (1), has been determined by single-crystal X-ray diffraction at 120 K. Its reactions with the platinum(II) dimers trans-[PtCl(mu-Cl)(PEt3)](2), trans-[PtCl(mu-Cl)(PPh2Me)](2), trans-[PtCl(mu-Cl)(PPh2Me2)](2) and trans-[PtBr(mu-Br)(PEt3)](2) have been investigated using P-31 NMR solution-state spectroscopy. Monomeric trans- and cis-Pt(II) complexes were formed: the molecular structures of cis-[PtCl2(L)(PR2R')] (R=R'=Et (3), R=Ph, R'=Me (7)), cis-[PtBr2L(PEt3)] (9) and cis-[PtCl2L2] (10), where L = 2,6-(CF3)(2)-C6H3-P(OCH2)(2), have been ascertained at 120 K.

机译：已通过单晶X-确定了2,6-（CF3）（2）-C6H3-P（OCH2）（2）（1）的2-芳基-1,3,2-二氧杂膦烷的分子结构。射线衍射在120 K时进行。使用P-31 NMR溶液态光谱法研究了-[PtCl（mu-Cl）（PPh2Me2）]（2）和反式[PtBr（mu-Br）（PEt3）]（2）。形成单体反式和顺式Pt（II）配合物：顺式[[PtCl2（L）（PR2R'）]]的分子结构（R = R'= Et（3），R = Ph，R'= Me（ 7）），其中L = 2,6-（CF3）（2）-C6H3-P（OCH2）（2）的顺式[PtBr2L（PEt3）]（9）和顺式[PtCl2L2]（10）在120 K下确定

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《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |2010年第1期|共7页
作者
Dillon KB; Goeta AE; Monks PK; Shepherd HJ;
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正文语种 eng
中图分类无机化学;
关键词
Phosphonite; Phospholane; Platinum(II) complexes; Molecular structures; Phosphorus NMR;

机译：亚膦酸酯;磷烷;铂（II）配合物;分子结构;磷核磁共振;

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1. The molecular structure of a 2-aryl-1,3,2-dioxaphospholane and its coordination behaviour towards platinum(II) species; molecular structures of four platinum(II) complexes [J] . Dillon KB, Goeta AE, Monks PK, Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2010,第1期

机译：2-芳基-1,3,2-二氧杂膦烷的分子结构及其对铂（II）物种的配位行为;四种铂（II）配合物的分子结构
2. Functionalized 1,1-ethene dithiolates as ligands, V. Synthesis and crystal structure of palladium(II) and platinum(II) complexes with dithioylidene barbituric acid ligands. Molecular structure of a 2,6-diaminopyridine-platinum(II) barbiturate complex [J] . Weigand W., Noth H., Krossing I., Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences . 1998,第10期

机译：功能化的1,1-乙烯二硫醇盐作为配体，V。带有二硫亚烷基巴比妥酸配体的钯（II）和铂（II）配合物的合成和晶体结构。 2,6-二氨基吡啶-铂（II）巴比妥酸酯络合物的分子结构
3. Intramolecular Stacking of Two Aromatic Rings in the Platinum (II0 Coordination Sphere:Preparation,Crystal Structures,and ~1H NMR Spectra of Bipyridine (N-arylmethyl-1,2-etanediamine)platinum(II)Nitrate [J] . Masafumi Goto, Takashi Matsumoto, Masamitsu Sumimoto, Bulletin of the Chemical Society of Japan . 2000,第1期

机译：硝酸双吡啶（N-芳基甲基-1,2-乙二胺）铂（II0）配体中两个芳香环的分子内堆积（II0配位球：晶体的结构，晶体结构和〜1H NMR光谱）
4. Elucidation of Excimer Formation of Phosphorescent Cyclometalated Platinum(II) Complexes at the Molecular Level [C] . Naoki Okamura, Takeshi Maeda, Hideki Fujiwara 日本化学会春季年会講演予稿集 . 2018

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5. Diphosphine platinum(II) binaphtholates: Structures and application to molecular imprinting and Lewis acid catalysis. [D] . Brunkan, Nicole M. 2001

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6. Hydrolysis of Methionine- and Histidine-Containing Peptides Promoted by Dinuclear Platinum(II) Complexes with Benzodiazines as Bridging Ligands: Influence of Ligand Structure on the Catalytic Ability of Platinum(II) Complexes [O] . Snežana Rajković, Beata Warżajtis, Marija D. Živković, 2018

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7. Síntese e caracterização de um novo complexo de platina (IV) a partir de seu análogo de platina (II) utilizando iodo molecular como agente oxidante: uma rota sintética interessante para obtenção de novos complexos de platina Synthesis and characterization of a novel platinum (IV) complex from its platinum (II) analogue using molecular iodine as an oxidizing agent: an interesting synthetic route for the preparation of new platinum complexes [O] . Wendell Guerra, Heveline Silva, Mauro Vieira de Almeida, 2007

机译：使用分子碘作为氧化剂从铂（II）类似物合成和表征新的铂（IV）络合物：获得新铂络合物的有趣合成途径合成和表征新型铂（IV）使用分子碘作为氧化剂的铂（II）类似物的复合物：一种用于制备新铂络合物的有趣合成途径
8. Crystal and Molecular Structures of a Tricyclic Phosphorus Ester, a Cobalt(III) Macrocyclic Complex and a Trans Coordinated Platinum(II) Compound [R] . Wintergrass, D. J. 1987

机译：三环磷酯，钴（III）大环配合物和反式配位铂（II）化合物的晶体和分子结构

The molecular structure of a 2-aryl-1,3,2-dioxaphospholane and its coordination behaviour towards platinum(II) species; molecular structures of four platinum(II) complexes

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