Palladium(II) and platinum(II) complexes of bidentate 2-pyridyl-1,2,3- triazole 'click' ligands: Synthesis, properties and X-ray structures

Kilpin K.J.; Crowley J.D.

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Palladium(II) and platinum(II) complexes of bidentate 2-pyridyl-1,2,3- triazole 'click' ligands: Synthesis, properties and X-ray structures

机译：二齿2-吡啶基-1,2,3-三唑“点击”配体的钯（II）和铂（II）配合物：合成，性质和X射线结构

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The synthesis and characterization of palladium(II) and platinum(II) complexes of isomeric bidentate 2-pyridyl-1,2,3-triazole "click" ligands is reported. The complexes have been fully characterized by elemental analysis, HRESI-MS, IR, UV-Vis, 1H and 13C NMR spectroscopy. Additionally, the molecular structures of the Pd(II) and Pt(II) complexes of the 2-[(4-phenyl-1H-1,2,3-triazol-1-yl)methyl]pyridine ligand are confired by X-ray crystallography. Solution studies indicate the 2-(1-benzyl-1H-1,2,3-triazol-4-yl)pyridine ligand forms more stable complexes with Pd(II) and Pt(II) than the isomeric 2-[(4-phenyl-1H-1,2,3-triazol-1-yl) methyl]pyridine ligand.

机译：报道了二齿双齿2-吡啶基-1,2,3-三唑“点击”配体的钯（II）和铂（II）配合物的合成和表征。通过元素分析，HRESI-MS，IR，UV-Vis，1H和13C NMR光谱对配合物进行了充分表征。此外，X [-]点燃了2-[（（4-苯基-1H-1,2,3-三唑-1-基）甲基]吡啶配体的Pd（II）和Pt（II）配合物的分子结构射线晶体学。溶液研究表明2-（1-苄基-1H-1,2,3-三唑-4-基）吡啶配体与Pd（II）和Pt（II）形成比异构体2-[（（4-苯基-1H-1,2,3-三唑-1-基）甲基]吡啶配体。

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《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |2010年第16期|共7页
作者
Kilpin K.J.; Crowley J.D.;
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正文语种 eng
中图分类无机化学;
关键词
1; 2; 3-Triazoles; Click; Gold(III); Palladium(II); Platinum(II); Pyridine;

机译：1;2;3-三唑;点击;金（III）;钯（II）;铂（II）;吡啶;

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Palladium(II) and platinum(II) complexes of bidentate 2-pyridyl-1,2,3- triazole 'click' ligands: Synthesis, properties and X-ray structures

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