Structural, spectroscopic and magnetic properties of new copper(II) complexes with a terpyridine ligand

Wa?sa-Chorab M.; Stefankiewicz A.R.; Gorczyński A.; Kubicki M.; K?ak J.; Korabik M.J.; Patroniak V.

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Structural, spectroscopic and magnetic properties of new copper(II) complexes with a terpyridine ligand

机译：具有三联吡啶配体的新型铜（II）配合物的结构，光谱和磁性

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Four mononuclear complexes of the dimethylterpyridine ligand 1,3-bis(6-methylpyridin-2-yl)pyridine, L, C_(17)H_(15)N _3, of the general formula CuLX2 were prepared from different copper(II) salts (X = Cl--1a, Br--1b, NO3 - 1c and ClO4 - 1d). Their properties have been characterized through analytical, spectroscopic (EPR, ESI-MS, and IR) and magnetic measurements. Single crystal X-ray structure analyses of these complexes revealed five-coordinate metal ions in 1a, 1b and 1c, whereas 1d turned out to contain a six-coordinate Cu(II) center and to have both unique magnetic and structural properties, rationalized in terms of the hydrogen-bonding interactions seen in its crystal lattice.

机译：从不同的铜（II）盐制备四甲基二甲基吡啶配体1,3-双（6-甲基吡啶-2-基）吡啶L，C_（17）H_（15）N_3的四个单核配合物（X ＝ Cl--1a，Br--1b，NO3-1c和ClO4-1d）。它们的性质已通过分析，光谱（EPR，ESI-MS和IR）和磁测量进行了表征。这些配合物的单晶X射线结构分析显示，在1a，1b和1c中存在五配位金属离子，而在1d中则包含了六配位的Cu（II）中心，并且具有独特的磁性和结构性质，这些元素在晶格中氢键相互作用的术语。

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来源
《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |2011年第2期|共8页
作者
Wa?sa-Chorab M.; Stefankiewicz A.R.; Gorczyński A.; Kubicki M.; K?ak J.; Korabik M.J.; Patroniak V.;
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正文语种 eng
中图分类无机化学;
关键词
Coordination modes; Copper; Magnetic properties;

机译：配位模式;铜;磁性能;

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1. Structural, spectroscopic and magnetic properties of new copper(II) complexes with a terpyridine ligand [J] . Wa?sa-Chorab M., Stefankiewicz A.R., Gorczyński A., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2011,第2期

机译：具有三联吡啶配体的新型铜（II）配合物的结构，光谱和磁性
2. Unusual trinuclear complex of copper(II) containing a 4 '-(3-methyl-2-thienyl)-4,2 ':6 ',4 ''-terpyridine ligand. Structural, spectroscopic, electrochemical and magnetic properties [J] . Toledo Dominique, Ahumada Guillermo, Manzur Carolina, Journal of Molecular Structure . 2017,第期

机译：铜（II）的不寻常的三核络合物，含有4' - （3-甲基-2-噻吩基）-4,2'：6'，4'' - 吡啶配体。结构，光谱，电化学和磁性
3. Comparitive study on structural, magnetic and spectroscopic properties of four new copper(II) coordination polymers with 4′-substituted terpyridine ligands [J] . Dominique Toledo, Andrés Vega, Nancy Pizarro, Journal of Solid State Chemistry . 2017,第期

机译：四种新型铜（II）配位聚合物的结构，磁性和光谱性能的比较研究
4. Structural characterization of vanadium terpyridine complexes for the study of in-situ ligand cyclization reaction [C] . Wan-Ting Jin, Zhao-Hui Zhou Joint Conference on Chemistry . 2019

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机译：I.某些咪唑基桥接铜（II）配合物的合成，溶液行为，晶体结构和磁性。二。含碳桥基的三铜（II）簇的晶体结构和磁性。
6. Spectroscopic structural and magnetic investigations of iron(II) complexes based on 1-isopropyl- and 1-isobutyl-substituted tetrazole ligands [O] . Nader Hassan, Julia Stelzl, Peter Weinberger, -1

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7. Comparitive study on structural, magnetic and spectroscopic properties of four new copper(II) coordination polymers with 4′-substituted terpyridine ligands [O] . Toledo, D., Vega, A., Pizarro, N., 2017

机译：四种具有4'-取代的三联吡啶配体的新型铜（II）配位聚合物的结构，磁性和光谱性质的比较研究

Structural, spectroscopic and magnetic properties of new copper(II) complexes with a terpyridine ligand

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