LANTHANIDE(III) COMPLEXES WITH BIDENTATE BIHETEROCYCLIC LIGANDS

Thakur P.; Dash KC.; Chakravortty V.

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LANTHANIDE(III) COMPLEXES WITH BIDENTATE BIHETEROCYCLIC LIGANDS

机译：双侧双杂环类化合物的镧系元素（III）配合物

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Eight lanthanide thiocyanate complexes of the type [Ln(NCS)(3)(PBH)(2)] and [Ln(NCS)(3)(MPB)(2)], where Ln = La, Pr, Nd, Sm, Eu, Gd, Dy and Y and PBH and MPB are 2-(2-pyriaylbenzimidazole) and 1-methyl-2-(2'-pyridyl)benzimidazole, respectively, have been synthesized and characterized by various physicochemical techniques such as conductance and thermogravimetric studies, electronic, IR, NMR (H-1 and C-13), EPR, CV and fluorescence spectral investigations. The nu(C=N) of the thiocyanate group indicates N coordination in all cases. (C) 1997 Elsevier Science Ltd. [References: 33]

机译：[Ln（NCS）（3）（PBH）（2）]和[Ln（NCS）（3）（MPB）（2）]类型的八种镧系元素硫氰酸盐络合物，其中Ln = La，Pr，Nd，Sm， Eu，Gd，Dy和Y以及PBH和MPB分别是2-（2-吡啶基苯并咪唑）和1-甲基-2-（2'-吡啶基）苯并咪唑，并已通过电导和热重分析等各种物理化学技术进行了表征研究，电子，IR，NMR（H-1和C-13），EPR，CV和荧光光谱研究。在所有情况下，硫氰酸酯基团的nu（C = N）均表示N配位。（C）1997 Elsevier Science Ltd. [参考：33]

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《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |1997年第9期|共8页
作者
Thakur P.; Dash KC.; Chakravortty V.;
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正文语种 eng
中图分类化学;无机化学;
关键词
Lanthanide complexes; Epr; Nmr; Fluorescence spectra; Thermogravimetric analysis; Cyclic voltammetry; Oxovanadium(iv) complexes; Thorium(iv) complexes; Dioxouranium(vi); 2-(2'-pyridyl)benzimidazole; Systems; Ions;

机译：镧系元素络合物;EPr;Nmr;荧光光谱;热重分析;循环伏安法;氧钒（iv）络合物;hor（iv）络合物;二氧杂鎓（vi）;2-（2'-吡啶基）苯并咪唑;体系;离子;

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1. LANTHANIDE(III) COMPLEXES WITH BIDENTATE BIHETEROCYCLIC LIGANDS [J] . Thakur P., Dash KC., Chakravortty V. Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 1997,第9期

机译：双侧双杂环类化合物的镧系元素（III）配合物
2. Synthesis and Characterization of Anionic Lanthanide(III) Complexes with a Bidentate Sulfonylamidophosphate (SAPh) Ligand [J] . Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2020,第1期

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4. Tuning Color of Charged Iridium(III) Complexes with a Spiro N,N'-Bidentate Ligand [C] . Kattaliya Mothajit, Kittiya Wongkhan, Rukkiat Jitchati International Conference on Mechanical and Electrical Technology . 2012

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6. Hydrophilic sulfonated bis-124-triazine ligands are highly effective reagents for separating actinides(iii) from lanthanides(iii) via selective formation of aqueous actinide complexes [O] . Frank W. Lewis, Laurence M. Harwood, Michael J. Hudson, 2015

机译：亲水的磺化双124-三嗪配体是通过选择性形成of系元素水合物从separating化物（iii）中分离act系元素（iii）的高效试剂
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机译：圆形和链条状铜（II）镧系元素（III）通过外消旋和手性铜（II）的组装反应产生的复合物与LNIII（NO 3）36H2O（LNIII = GDIII，TBIII，DYIII）交联配体复合物

LANTHANIDE(III) COMPLEXES WITH BIDENTATE BIHETEROCYCLIC LIGANDS

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