Complexes of Zn(II) containing (o-)/(p-) carboxylato phenyl azo pentane 2,4-dione and 2,2′ bipyridine as ligands: Synthesis, characterization, colorimetric and fluorometric modulation in the presence of Ag~+ ions

Amin Hasan M.; Kumari N.; Kumar P.; Pathak B.; Mishra L.

首页> 外文期刊>Polyhedron: The International Journal for Inorganic and Organometallic Chemistry >Complexes of Zn(II) containing (o-)/(p-) carboxylato phenyl azo pentane 2,4-dione and 2,2′ bipyridine as ligands: Synthesis, characterization, colorimetric and fluorometric modulation in the presence of Ag~+ ions

【24h】

Complexes of Zn(II) containing (o-)/(p-) carboxylato phenyl azo pentane 2,4-dione and 2,2′ bipyridine as ligands: Synthesis, characterization, colorimetric and fluorometric modulation in the presence of Ag~+ ions

机译：含（o-）/（p-）羧基苯基苯基偶氮戊烷2,4-二酮和2,2'联吡啶作为配体的Zn（II）配合物：在Ag〜+离子存在下的合成，表征，比色和荧光调制

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Azo-enol based ligands 2-[N′-(1-acetyl-2-oxo-propylidene) hydrazino]-benzoic acid (L_1H_2) and 4-[N′-(1 acetyl-2 oxo-propylidene)-hydrazino]-benzoic acid (L_2H_2) and their complexes [Zn(L_1H)_2(bpy)] (1) and [Zn(L _2H)_2(bpy)] (2) (where bpy = 2, 2′-bipyridine) have been synthesized and characterized using elemental analyses, spectral (FT-IR, 1H NMR, ~(13)C NMR, electronic absorption), emission and single-crystal X-ray diffraction studies. Complexes 1 and 2 display selective chromogenic and fluorogenic responses with Ag~+ ions in the presence of several other metal ions. The binding is monitored separately using UV-Vis, fluorescence and ~1H NMR spectral titrations. Job's plot supports a 1:2 stoichiometry for 1 and 2 with Ag~+ ions. The pH dependent "on-off" switching of fluorescence from complexes 1 and 2 have been studied. The fluorescence intensity quenches (turns-off) upon addition of OH~- ions, while it enhances (turns-on) in the presence of H ~+ ions.

机译：基于偶氮烯醇的配体2- [N'-（1-乙酰基-2-氧代亚丙基）肼基]-苯甲酸（L_1H_2）和4- [N'-（1乙酰基-2-氧代亚丙基）肼基]-已合成苯甲酸（L_2H_2）及其配合物[Zn（L_1H）_2（bpy）]（1）和[Zn（L _2H）_2（bpy）]（2）（其中bpy = 2，2'-联吡啶）并使用元素分析，光谱（FT-IR，1H NMR，〜（13）C NMR，电子吸收），发射和单晶X射线衍射研究表征。配合物1和2在几种其他金属离子的存在下，对Ag〜+离子表现出选择性的生色和荧光反应。使用UV-Vis，荧光和〜1H NMR光谱滴定分别监测结合。乔布的图支持Ag〜+离子对1和2的化学计量比为1：2。已经研究了复合物1和2的pH依赖性“开-关”荧光转换。加入OH〜-离子后，荧光强度猝灭（熄灭），而在存在H〜+离子时，荧光强度增强（点亮）。

著录项

来源
《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |2013年第1期|共8页
作者
Amin Hasan M.; Kumari N.; Kumar P.; Pathak B.; Mishra L.;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类无机化学;
关键词
Azodiketone; Spectral titration; Switching of optical signal; X-ray diffraction; Zn(II) complex;

机译：偶氮二酮;光谱滴定;光信号转换;X射线衍射;Zn（II）配合物;

相似文献

外文文献
中文文献
专利

1. Complexes of Zn(II) containing (o-)/(p-) carboxylato phenyl azo pentane 2,4-dione and 2,2′ bipyridine as ligands: Synthesis, characterization, colorimetric and fluorometric modulation in the presence of Ag~+ ions [J] . Amin Hasan M., Kumari N., Kumar P., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2013,第1期

机译：含（o-）/（p-）羧基苯基苯基偶氮戊烷2,4-二酮和2,2'联吡啶作为配体的Zn（II）配合物：在Ag〜+离子存在下的合成，表征，比色和荧光调制
2. Synthesis and Characterization of the Complexes of Pentane-2,4-dione with Nickel(II) and Cobalt(III): [Ni(acac)2]·0.5CH3OH and [Co(acac)2NO3]·2H2O (acac = Pentane-2,4-dione) [J] . Molecules . 2004,第11期

机译：戊烷-2,4-二酮与镍（II）和钴（III）：[Ni（acac）2]·0.5CH3OH和[Co（acac）2NO3]·2H2O（acac = Pentane- 2,4-二酮）
3. Transition metal complexes with thiosemicarbazide-based ligands. Part. 34. Synthesis, spectroscopic and voltammetric characterization of Ni(II) and Ni(III) complexes with tetra-and octadentate pentane -2,4-dione -bis)S-methylisothiosemicarba- zone)-d [J] . LIJLJANA S. JOVANOVIC, VUKADIN M. LEOVAC, MIRJANA M. POPSAVIN Journal of the Serbian Chemical Society . 1997,第6期

机译：过渡金属配合物与基于硫代氨基脲的配体。部分。 34.具有四齿和八齿戊烷-2,4-二酮-双）S-甲基异硫代半碳酰胺-区的Ni（II）和Ni（III）配合物的合成，光谱和伏安特性
4. Synthesis and Characterization of the Monomeric Platinum (II) Complexes with 2,2'-Bipyridine Back-bone Ligand [C] . Minchul Chung, Woong Kyu Jo, Seak Hwan Son, International Conference on Chemical Engineering and Advanced Materials . 2012

机译：用2,2'-硼吡啶背骨配体的单体铂（II）配合物的合成与表征
5. Synthesis and characterization of novel platinum(II) and platinum(IV) complexes containing 4,4'-disubstituted-2,2'- bipyridine ligands for the treatment of cancer. [D] . Vo, Van. 2014

机译：含有4,4'-双取代-2,2'-联吡啶配体的新型铂（II）和铂（IV）配合物的合成和表征，用于治疗癌症。
6. Studies on Some New Ru(III) Complexes Using aryl-azo Pentane-2,4-dione and 2,6-bis (2'-Benzimidazolyl) Pyridine as Ligands:Synthesis, Spectroscopic, Luminescent, Electrochemical and Biological Activities [O] . Lallan Mishra, Ajay K. Yadaw, Ratna S. Phadke, 1947

机译：用芳基偶氮戊烷-研究一些新的Ru（III）配合物2,4-二酮和2,6-双（2'-苯并咪唑基）吡啶为配体：合成，光谱，发光，电化学和生物活性
7. Studies on Some New Ru(III) Complexes Using aryl-azo Pentane- 2,4-dione and 2,6-bis (2'-Benzimidazolyl) Pyridine as Ligands: Synthesis, Spectroscopic, Luminescent, Electrochemical and Biological Activities [O] . Mishra, Lallan, Yadaw, Ajay K., Phadke, Ratna S., 2001

机译：用芳基偶氮戊烷-研究一些新的Ru（III）配合物 2,4-二酮和2,6-双（2'-苯并咪唑基）吡啶为配体：合成，光谱，发光，电化学和生物活性
8. Solvent Dependence of Metal-to-Ligand Charge-Transfer Transitions. Evidence for Initial Electron Localization in MLCT Excited States of 2,2'-Bipyridine Complexes of Ru(II) And Os(II) [R] . Kober, E. M., Sullivan, B. P., Meyer, T. J. 1983

机译：金属与配体电荷转移跃迁的溶剂依赖性。 Ru（II）和Os（II）2,2'-联吡啶配合物mLCT激发态初始电子定位的证据

Complexes of Zn(II) containing (o-)/(p-) carboxylato phenyl azo pentane 2,4-dione and 2,2′ bipyridine as ligands: Synthesis, characterization, colorimetric and fluorometric modulation in the presence of Ag~+ ions

摘要

著录项

相似文献

相关主题

期刊订阅