Crystal structure and topological ferrimagnetic behavior of a new 2D metal-organic hybrid manganese complex [Mn_3(N_3) _4(L)_2(H_2O)_2]_n·0. 6(C_2H_5OH)·1.4(H_2O) with the AF/AF/F alternating sequence (HL = N′-((pyridine-2-yl)methylene) isonicotinohydrazide)

Shaabani B.; Khandar A.A.; Kazemi S.S.; Shaghaghi Z.; Boudalis A.K.; Psycharis V.; Raptopoulou A.

首页> 外文期刊>Polyhedron: The International Journal for Inorganic and Organometallic Chemistry >Crystal structure and topological ferrimagnetic behavior of a new 2D metal-organic hybrid manganese complex [Mn_3(N_3) _4(L)_2(H_2O)_2]_n·0. 6(C_2H_5OH)·1.4(H_2O) with the AF/AF/F alternating sequence (HL = N′-((pyridine-2-yl)methylene) isonicotinohydrazide)

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Crystal structure and topological ferrimagnetic behavior of a new 2D metal-organic hybrid manganese complex [Mn_3(N_3) _4(L)_2(H_2O)_2]_n·0. 6(C_2H_5OH)·1.4(H_2O) with the AF/AF/F alternating sequence (HL = N′-((pyridine-2-yl)methylene) isonicotinohydrazide)

机译：新型二维有机金属杂化锰配合物[Mn_3（N_3）_4（L）_2（H_2O）_2] _n·0的晶体结构和拓扑亚铁磁行为。具有AF / AF / F交替顺序的6（C_2H_5OH）·1.4（H_2O）（HL = N'-（（吡啶-2-基）亚甲基）异烟酰肼）

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The reaction of manganese(II) and N′-((pyridine-2-yl)methylene) isonicotinohydrazide) led to the formation of a new 2D system, [Mn _3(N_3)_4(L)_2(H_2O) _2]_n·0.6(C_2H_5OH)·1. 4(H_2O). This compound crystallizes in the triclinic system, space group P1? with a = 8.2826(1), b = 9.2192(1), c = 11.2243(2) ? parameters, Z = 1. X-ray crystallographic data show that the azido groups act as bridges between neighboring manganese atoms, with the [-{L-Mn-(μ _(1,3)-N_3)_2-Mn-L}-(μ_(1,3)-N _3)-{Mn(1)-(OW(1))_2}-(μ_(1,1)-N _3)_2-]_n sequence forming chains which are extended into 2D layers through Mn to nitrogen atom bonding lying at the para position of the pyridine group of the ligand L. Analysis of the magnetic data reveals that the EO and EE azido bridges mediate ferromagnetic and antiferromagnetic interactions, respectively. Interestingly, this complex exhibits a ferrimagnetic-like behavior.

机译：锰（II）与N'-（（吡啶-2-基）亚甲基）异烟酰肼的反应导致形成新的二维系统[Mn _3（N_3）_4（L）_2（H_2O）_2] _n ·0.6（C_2H_5OH）·1。 4（H_2O）。该化合物在三斜晶系空间群P1？其中a = 8.2826（1），b = 9.2192（1），c = 11.2243（2）？参数Z =1。X射线晶体学数据显示，叠氮基团充当相邻锰原子之间的桥梁，[-{L-Mn-（μ_（1,3）-N_3）_2-Mn-L} -（μ_（1,3）-N _3）-{Mn（1）-（OW（1））_ 2}-（μ_（1,1-N _3）_2-] _ n形成序列的链延伸到通过Mn和氮原子键合的二维层位于配体L吡啶基的对位。对磁性数据的分析表明，EO和EE叠氮基桥分别介导铁磁和反铁磁相互作用。有趣的是，该复合物表现出类似铁磁的行为。

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《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |2013年第1期|共6页
作者
Shaabani B.; Khandar A.A.; Kazemi S.S.; Shaghaghi Z.; Boudalis A.K.; Psycharis V.; Raptopoulou A.;
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正文语种 eng
中图分类无机化学;
关键词
Azido bridges; Crystal structure; Magnetic properties; Manganese(II) complexes;

机译：叠氮桥;晶体结构;磁性;锰（II）配合物;

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外文文献

1. Crystal structure and topological ferrimagnetic behavior of a new 2D metal-organic hybrid manganese complex [Mn_3(N_3) _4(L)_2(H_2O)_2]_n·0. 6(C_2H_5OH)·1.4(H_2O) with the AF/AF/F alternating sequence (HL = N′-((pyridine-2-yl)methylene) isonicotinohydrazide) [J] . Shaabani B., Khandar A.A., Kazemi S.S., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2013,第1期

机译：新型二维有机金属杂化锰配合物[Mn_3（N_3）_4（L）_2（H_2O）_2] _n·0的晶体结构和拓扑亚铁磁行为。具有AF / AF / F交替顺序的6（C_2H_5OH）·1.4（H_2O）（HL = N'-（（吡啶-2-基）亚甲基）异烟酰肼）
2. Topological ferrimagnetic behavior of two new [Mn(L)(2)(N-3)(2)](n) chains with the new AF/AF/F alternating sequence (L=3-methylpyridine or 3,4-dimethylpyridine) [J] . Abu-Youssef MAM., Escuer A., Goher MAS., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2000,第22期

机译：具有新的AF / AF / F交替序列（L = 3-甲基吡啶或3,4-二甲基吡啶）的两个新[Mn（L）（2）（N-3）（2）]（n）链的拓扑铁磁行为
3. Topological ferrimagnetic behavior of one new chain with the new AF/F/F'/F'/F alternating sequence [J] . Joan Cano, Yves Journaux, Mohamed A.S.Goner, New Journal of Chemistry . 2005,第2期

机译：具有新的AF / F / F'/ F'/ F交替序列的一条新链的拓扑铁磁行为

Crystal structure and topological ferrimagnetic behavior of a new 2D metal-organic hybrid manganese complex [Mn_3(N_3) _4(L)_2(H_2O)_2]_n·0. 6(C_2H_5OH)·1.4(H_2O) with the AF/AF/F alternating sequence (HL = N′-((pyridine-2-yl)methylene) isonicotinohydrazide)

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