Electrochemical behaviour of [Ru(4,4 '-Me(2)bpy)(2)(PPh3)(H2O)](ClO4)(2) in homogeneous solution and incorporated into a carbon paste electrode. Application to oxidations of benzylic compounds

Lima EC.; Romero JR.; De Giovani WF.; Fenga PG.

首页> 外文期刊>Polyhedron: The International Journal for Inorganic and Organometallic Chemistry >Electrochemical behaviour of [Ru(4,4 '-Me(2)bpy)(2)(PPh3)(H2O)](ClO4)(2) in homogeneous solution and incorporated into a carbon paste electrode. Application to oxidations of benzylic compounds

【24h】

Electrochemical behaviour of [Ru(4,4 '-Me(2)bpy)(2)(PPh3)(H2O)](ClO4)(2) in homogeneous solution and incorporated into a carbon paste electrode. Application to oxidations of benzylic compounds

机译：[Ru（4,4'-Me（2）bpy）（2）（PPh3）（H2O）]（ClO4）（2）在均匀溶液中的电化学行为，并掺入碳糊电极中。在苄基化合物的氧化中的应用

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The complex [Ru(4,4'-Me(2)bpy)(2)(PPh3)(H2O)](ClO4)(2) has been synthesized and characterized by elemental analysis, spectroscopic and electrochemical methods. E-1/2 vs pH studies are consistent with one-electron, one-proton transfer; at higher pH the potentials become pH independent. The catalytic activity of the complex has been investigated at pH 6.5 in the homogeneous electrooxidation of benzylic compounds. The reactivity was found to decrease in the order 1-phenylethanol much greater than phthalic alcohol > benzyl alcohol > 4-methylbenzyl alcohol > ethylbenzene > toluene. Carbon paste electrode (CPE) containing the complex has shown catalytic activity in oxidations of alcohols. Benzyl alcohol oxidation by CPE is first order on substrate concentration and for low concentrations is controlled by the diffusion rate of the substrate from solution. (C) 1997 Elsevier Science Ltd. [References: 29]

机译：合成了[Ru（4,4'-Me（2）bpy）（2）（PPh3）（H2O）]（ClO4）（2），并通过元素分析，光谱和电化学方法对其进行了表征。 E-1 / 2与pH的研究与单电子，质子转移是一致的;在较高的pH值下，电位变得与pH无关。在苄基化合物的均相电氧化中，已在pH 6.5下研究了配合物的催化活性。发现反应性以1-苯乙醇的顺序降低，其幅度远大于邻苯二甲酸醇>苯甲醇> 4-甲基苯甲醇>乙苯>甲苯。含有络合物的碳糊电极（CPE）在醇的氧化中显示出催化活性。 CPE催化的苄醇氧化是底物浓度的一级反应，对于低浓度，其受底物从溶液中的扩散速度控制。（C）1997 Elsevier Science Ltd. [参考：29]

著录项

来源
《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |1998年第3期|共6页
作者
Lima EC.; Romero JR.; De Giovani WF.; Fenga PG.;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学;无机化学;
关键词

相似文献

外文文献
中文文献
专利

1. Electrochemical behaviour of [Ru(4,4 '-Me(2)bpy)(2)(PPh3)(H2O)](ClO4)(2) in homogeneous solution and incorporated into a carbon paste electrode. Application to oxidations of benzylic compounds [J] . Lima EC., Romero JR., De Giovani WF., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 1998,第2a3期

机译：[Ru（4,4'-Me（2）bpy）（2）（PPh3）（H2O）]（ClO4）（2）在均匀溶液中的电化学行为，并掺入碳糊电极中。在苄基化合物的氧化中的应用
2. Synthesis, spectroscopic and electrochemical properties of some heteroleptic tris-chelates of ruthenium(II) involving 2,2 '-bipyridine (bpy) and N-(aryl)pyridine-2-aldimine(L): X-ray crystal structures of [Ru(bpy)(L-2)(2)](ClO4)(2)center dot H2O and [J] . Mishra D, Naskar S, Adhikary B, Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2005,第2期

机译：某些涉及2,2'-联吡啶（bpy）和N-（芳基）吡啶-2-醛二胺（L）的钌（II）杂配三螯合物的合成，光谱和电化学性质：[Ru] X射线晶体结构（bpy）（L-2）（2）]（ClO4）（2）中心点H2O和
3. SELECTIVE SYNTHESIS AND ELECTROCHEMICAL BEHAVIOR OF TRANS(CL)- AND CIS(CL)-[RU(BPY)(CO)(2)CL-2] COMPLEXES (BPY = 2,2'-BIPYRIDINE) - COMPARATIVE STUDIES OF THEIR ELECTROCATALYTIC ACTIVITY TOWARD THE REDUCTION OF CARBON DIOXIDE [J] . Chardonnoblat S., Ziessel R., Zsoldos D., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 1997,第23期

机译：反式（CL）-和CIS（CL）-[RU（BPY）（CO）（2）CL-2]复合物（BPY = 2,2'-BIPYRIDINE）的选择性合成和电化学行为-其电催化活性的比较研究致力于减少二氧化碳的排放
4. MECHANICAL AND INTERFACIAL PROPERTIES OF CARBON FIBER MODIFIED BY ELECTROCHEMICAL OXIDATION IN (NH4HCO3)/(NH4)2C2O4·H2O AQUEOUS COMPOUND SOLUTION [C] . Yuli Tian, Jie Liu, Jieying Liang Annual World Conference on Carbon . 2010

机译：（NH4HCO3）/（NH4）/（NH4）2C204·H2O水合物溶液中电化学氧化改性碳纤维的机械和界面性能
5. Oxidation of Organic Substrates in Aqueous Micellar Media Synthesis, Characterization and Application of N-alkyliminodiacetato Compounds for the Oxidation of Phenol and Carbon-Carbon Coupling of 2,6-di-tert-butylphenol in Aqueous Micellar Solutions. [D] . Cull, John Eli William. 2012

机译：胶束水溶液中有机底物的氧化胶束水溶液中2,6-二叔丁基苯酚的苯酚氧化和碳-碳偶联的N-烷基亚氨基二乙酰基化合物的合成，表征和应用。
6. A Two-Dimensional Square Network Inclusion Compound Incorporating Guest Molecules Through Both Hydrogen Bonding and Nonionic Electrostatic Attraction. Crystal Structure of Cd(4,4'-bpy)2(H2O)2-(ClO4)2.1.5(4,4'-bpy).(C6H4NO3Cl).H2O. [O] . Cai-Ming Liu, Ren-Gen Xiong, Xiao-Zeng You, 1998

机译：通过氢键合和非离子静电吸引力掺入客体分子的二维方形网络包合物化合物。 Cd（4,4'-BPY）2（H2O）2 - （CLO 4）2的晶体结构2.1.5（4,4'-BPY）。（C6H4NO3CL）.h2O。

Electrochemical behaviour of [Ru(4,4 '-Me(2)bpy)(2)(PPh3)(H2O)](ClO4)(2) in homogeneous solution and incorporated into a carbon paste electrode. Application to oxidations of benzylic compounds

摘要

著录项

相似文献

相关主题

期刊订阅