MIXED-LIGAND COMPLEXES OF INDIUM(III) - REACTIONS OF [INCL3(L-1)(MEOH)] WITH BIDENTATE LIGANDS - SYNTHESIS, CHARACTERIZATION AND X-RAY STRUCTURES OF [IN(L-1)CL(OX)(OH2)]CENTER-DOT-2H(2)O, [IN(L-1)CL(MNT)]CENTER-DOT-MEOH AND [IN(PYTHIO)(3)] [L-1 EQUAL

Abram S.; Abram U.; Maichlemossmer C.

首页> 外文期刊>Polyhedron: The International Journal for Inorganic and Organometallic Chemistry >MIXED-LIGAND COMPLEXES OF INDIUM(III) - REACTIONS OF [INCL3(L-1)(MEOH)] WITH BIDENTATE LIGANDS - SYNTHESIS, CHARACTERIZATION AND X-RAY STRUCTURES OF [IN(L-1)CL(OX)(OH2)]CENTER-DOT-2H(2)O, [IN(L-1)CL(MNT)]CENTER-DOT-MEOH AND [IN(PYTHIO)(3)] [L-1 EQUAL

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MIXED-LIGAND COMPLEXES OF INDIUM(III) - REACTIONS OF [INCL3(L-1)(MEOH)] WITH BIDENTATE LIGANDS - SYNTHESIS, CHARACTERIZATION AND X-RAY STRUCTURES OF [IN(L-1)CL(OX)(OH2)]CENTER-DOT-2H(2)O, [IN(L-1)CL(MNT)]CENTER-DOT-MEOH AND [IN(PYTHIO)(3)] [L-1 EQUAL

机译：铟（III）的配体络合物-[INCL3（L-1）（MEOH）]与双齿配体的反应-[IN（L-1）CL（OX）（OH2）的合成，表征和X射线结构] CENTER-DOT-2H（2）O，[IN（L-1）CL（MNT）] CENTER-DOT-MEOH和[IN（PYTHIO）（3）] [L-1等式

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InCl3(L-1)(MeOH)] [L-1 = pyridine-2,6-bis(acetyloxime), 2,6-C5H3N(C2H3NOH)(2)] reacts with bidentate ligands by ligand exchange. A seven-coordinate complex of the composition [In(L-1)Cl(ox)(OH2)] is formed with potassium oxalate (K(2)ox). The oxalato ligand occupies the equatorial plane of a pentagonal bipyramid together with the tridentate amine oxime. With sodium 1,2-dicyanoethene-1,2-dithiolate (Na(2)mnt) the analogous reaction produces a six-coordinate mixed ligand complex, [In(L-1)Cl(mnt)], which has a distorted octahedral coordination sphere. Ligands which form four-membered chelate rings like dialkyldithiocarbamates, R(2)dtc(-), or pyridine-2-thiolate, pythio(-), are able to replace all ligands of [InCl3(L-1)(MeOH)] to form neutral tris chelates. The structure of [In(pythio)(3)] has been elucidated showing a strong distortion of the coordination polyhedron from the idealized octahedral geometry. (C) 1997 Elsevier Science Ltd. [References: 16

机译：InCl3（L-1）（MeOH）] [L-1 =吡啶-2,6-双（乙酰肟），2,6-C5H3N（C2H3NOH）（2）]通过配体交换与二齿配体反应。与草酸钾（K（2）ox）形成组成[In（L-1）Cl（ox）（OH2）]的七坐标络合物。草酸酯配体与三齿胺肟一起占据五角双锥体的赤道平面。与1,2-二氰基乙烯-1，2-二硫代硫酸钠（Na（2）mnt）相似，反应生成六配位混合配体络合物[In（L-1）Cl（mnt）]，其八面体变形协调领域。形成四元螯合环的配体，例如二烷基二硫代氨基甲酸酯R（2）dtc（-）或吡啶-2-硫代吡啶盐pythio（-），能够取代[InCl3（L-1）（MeOH）]的所有配体形成中性的tris螯合物。阐明[In（pythio）（3）]的结构表明配位多面体由于理想的八面体几何形状而发生了强烈变形。（C）1997 Elsevier Science Ltd [参考：16

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《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |1997年第13期|共8页
作者
Abram S.; Abram U.; Maichlemossmer C.;
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正文语种 eng
中图分类化学;无机化学;
关键词
Indium; Mixed-ligand complexes; Nitrogen donor ligands; X-ray structures;

机译：铟;配体配合物;氮供体配体;X射线结构;

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1. MIXED-LIGAND COMPLEXES OF INDIUM(III) - REACTIONS OF [INCL3(L-1)(MEOH)] WITH BIDENTATE LIGANDS - SYNTHESIS, CHARACTERIZATION AND X-RAY STRUCTURES OF [IN(L-1)CL(OX)(OH2)]CENTER-DOT-2H(2)O, [IN(L-1)CL(MNT)]CENTER-DOT-MEOH AND [IN(PYTHIO)(3)] [L-1 EQUAL [J] . Abram S., Abram U., Maichlemossmer C. Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 1997,第13期

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MIXED-LIGAND COMPLEXES OF INDIUM(III) - REACTIONS OF [INCL3(L-1)(MEOH)] WITH BIDENTATE LIGANDS - SYNTHESIS, CHARACTERIZATION AND X-RAY STRUCTURES OF [IN(L-1)CL(OX)(OH2)]CENTER-DOT-2H(2)O, [IN(L-1)CL(MNT)]CENTER-DOT-MEOH AND [IN(PYTHIO)(3)] [L-1 EQUAL

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