Supramolecular self-assembly in triphenyllead(IV) dimethylphosphinodithioate, (1)(x)[Ph3PbS2PMe2], a chain polymer built through intermolecular Pb center dot center dot center dot S secondary bonds

Edelmann FT.; Silvestru C.; Schmidt HG.; Noltemeyer M.; Haiduc I.

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Supramolecular self-assembly in triphenyllead(IV) dimethylphosphinodithioate, (1)(x)[Ph3PbS2PMe2], a chain polymer built through intermolecular Pb center dot center dot center dot S secondary bonds

机译：在三苯基铅（IV）二甲基次膦酸二硫代酸酯中的超分子自组装，（1）（x）[Ph3PbS2PMe2]，通过分子间Pb中心点中心点中心点S次级键构建的链状聚合物

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0The first structural characterization of an organolead phosphinodithioate is reported. According to an X-ray diffraction study, the title compound triphenyllead(IV) dimethylphosphinodithioate, (1)(x)[Ph3PbS2PMe2], forms a linear polymer in the solid state. Supramolecular association through secondary bonds of the type P=S ... Pb leads to a polymeric chain formed by -Pb-S-P=S ... Pb- units. The inorganic backbone is wrapped in a lipophilic "hose" made up of methyl and phenyl groups. (C) 1998 Elsevier Science Ltd. All rights reserved. [References: 21]

机译：0报道了有机膦二硫代铅的第一结构表征。根据X射线衍射研究，标题化合物三苯基铅（IV）二甲基次膦酸二硫酯（1）（x）[Ph3PbS2PMe2]形成固态的线性聚合物。通过类型P ＝ S ... Pb的次级键的超分子缔合导致由-Pb-S-P ＝ S ... Pb-单元形成的聚合物链。无机骨架被包裹在由甲基和苯基组成的亲脂性“软管”中。（C）1998 Elsevier ScienceLtd。保留所有权利。 [参考：21]

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《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |1998年第12期|共5页
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Edelmann FT.; Silvestru C.; Schmidt HG.; Noltemeyer M.; Haiduc I.;
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中图分类化学;无机化学;
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1. Supramolecular self-assembly in triphenyllead(IV) dimethylphosphinodithioate, (1)(x)[Ph3PbS2PMe2], a chain polymer built through intermolecular Pb center dot center dot center dot S secondary bonds [J] . Edelmann FT., Silvestru C., Schmidt HG., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 1998,第11a12期

机译：在三苯基铅（IV）二甲基次膦酸二硫代酸酯中的超分子自组装，（1）（x）[Ph3PbS2PMe2]，通过分子间Pb中心点中心点中心点S次级键构建的链状聚合物
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Supramolecular self-assembly in triphenyllead(IV) dimethylphosphinodithioate, (1)(x)[Ph3PbS2PMe2], a chain polymer built through intermolecular Pb center dot center dot center dot S secondary bonds

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