A new coordination mode for the tartrato ligand. Synthesis of vanadium(V) oxo peroxo tartrato complexes and the x-ray crystal structure of K-2[{VO(O-2)(L-tartH(2))}(2)(mu-H2O)].5H(2)O

Schwendt P.; Kuchta L.; Marek J.; Svancarek P.

首页> 外文期刊>Polyhedron: The International Journal for Inorganic and Organometallic Chemistry >A new coordination mode for the tartrato ligand. Synthesis of vanadium(V) oxo peroxo tartrato complexes and the x-ray crystal structure of K-2[{VO(O-2)(L-tartH(2))}(2)(mu-H2O)].5H(2)O

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A new coordination mode for the tartrato ligand. Synthesis of vanadium(V) oxo peroxo tartrato complexes and the x-ray crystal structure of K-2[{VO(O-2)(L-tartH(2))}(2)(mu-H2O)].5H(2)O

机译：酒石配体的新配位模式。钒（V）过氧羰基酒石配合物的合成和K-2 [{VO（O-2）（L-tartH（2））}（2）（mu-H2O）]。5H（ 2）O

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Vanadium(V) oxo peroxo tartrate complexes M-2[{VO(O-2)(L-tartH(2))}(2)(mu-H2O)]. 5H(2)O (M = K+, NH4+; tart(4-) = C4O6H24-) have been prepared from aqueous-ethanolic medium and characterized by elemental analysis and IR spectroscopy. The X-ray crystal structure of K-2[{VO(O-2) (L-tartH(2))}(2)(mu-H2O)]. 5H(2)O, as the first crystal structure of a vanadium(V) tartrate complex has been determined. The dinuclear anion exhibits two pentagonal bipyramidal polyhedra about vanadium atoms which are joined to each other by sharing two oxygen atoms of hydroxyl groups and oxygen atom from water molecule. The tartrate group is bonded to the vanadium atom in a bidentate way via oxygen atoms of neighbouring carboxylic and hydroxyl groups. The coordinated hydroxyl oxygen atom is bonded also to the second vanadium atom, but in a monodentate way. This type of bonding of tartrate group was not observed so far. (C) 1998 Elsevier Science Ltd. All rights reserved. [References: 22]

机译：钒（V）过氧过氧酒石酸钒络合物M-2 [{VO（O-2）（L-tartH（2））}（2）（mu-H2O）]。 5H（2）O（M = K +，NH4 +; art（4-）= C4O6H24-）已从乙醇水溶液中制备并通过元素分析和红外光谱进行了表征。 K-2 [{VO（O-2）（L-tartH（2））}（2）（mu-H2O）]的X射线晶体结构。作为酒石酸钒（V）络合物的第一晶体结构已确定为5H（2）O。双核阴离子表现出两个围绕钒原子的五边形双锥体多面体，它们通过共享两个羟基的氧原子和水分子中的氧原子相互连接。酒石酸根基团通过相邻的羧基和羟基的氧原子以二齿方式与钒原子键合。配位的羟基氧原子也与第二钒原子键合，但是以单齿方式。到目前为止，未观察到这种酒石酸基团的键合。（C）1998 Elsevier ScienceLtd。保留所有权利。 [参考：22]

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《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |1998年第14期|共6页
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Schwendt P.; Kuchta L.; Marek J.; Svancarek P.;
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1. A new coordination mode for the tartrato ligand. Synthesis of vanadium(V) oxo peroxo tartrato complexes and the x-ray crystal structure of K-2[{VO(O-2)(L-tartH(2))}(2)(mu-H2O)].5H(2)O [J] . Schwendt P., Kuchta L., Marek J., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 1998,第13a14期

机译：酒石配体的新配位模式。钒（V）过氧羰基酒石配合物的合成和K-2 [{VO（O-2）（L-tartH（2））}（2）（mu-H2O）]。5H（ 2）O
2. Synthesis and characterization of vanadium(IV) and (V) complexes with 2-hydroxy-acetophenone-semicarbazone (H(2)hasc) as ligand. X-ray crystal structures of [VO2(H(2)hasc)] and [VO2(Hhasc)] [J] . Maia PID, Deflon VM, de Sousa GF, Zeitschrift fur Anorganische und Allgemeine Chemie . 2007,第5a6期

机译：钒（IV）和（V）配合物与2-羟基苯乙酮-半卡巴zone（H（2）hasc）作为配体的合成和表征。 [VO2（H（2）hasc）]和[VO2（Hhasc）]的X射线晶体结构
3. Stereospecific formation of alpha-hydroxycarboxylato oxo peroxo complexes of vanadium(V). Crystal structure of (NBu4)(2)[V2O2(O-2)(2)-(L-lact)(2)]center dot 2H(2)O and (NBu4)(2)[V2O2(O-2)(2)(D-lact) (L-lact)]center dot 2H(2)O [J] . Schwendt P., Smatanova I., Marek J., Journal of Inorganic Biochemistry: An Interdisciplinary Journal . 2000,第1a2期

机译：钒（V）的α-羟基羧基氧代过氧配合物的立体定向形成。（NBu4）（2）[V2O2（O-2）（2）-（L-乳酸）（2）]中心点2H（2）O和（NBu4）（2）[V2O2（O-2）的晶体结构（2）（D-乳酸）（L-乳酸）]中心点2H（2）O
4. Hydrothermal Syntheses and X-ray Crystal Structure of Two Vanadium Selenites,{VO(OH)(H2O)(SeO3)}4· 2H2O and (H3NCH2CH2NH3)· (VO)(SeO3)2 [C] . International symposium on solid state chemistry in China amp; 8th Chinese national conference on solid state chemistry and inorganic synthesis : Book of abstracts . 2002

机译：两种钒亚硒酸盐{VO（OH）（H2O）（SeO3）} 4·2H2O和（H3NCH2CH2NH3）·（VO）（SeO3）2的水热合成和X射线晶体结构
5. Reactivity of sandwich pi-complexes towards dithiocarboxylic acids: Synthesis and x-ray crystallographic studies of titanium, vanadium, and niobium inorganic/organometallic sulfur-containing complexes [D] . Andras, Maria Theresa. 1990

机译：三明治型pi配合物对二硫代羧酸的反应活性：钛，钒和铌无机/有机金属含硫配合物的合成和x射线晶体学研究
6. Synthesis characterization and crystal structure of aquabis(44′-dimethoxy-22′-bipyridine)μ-(2R3R)-tartrato(4−)dicopper(II) octahydrate [O] . Dennis Wiedemann, Roman-David Kulko, Andreas Grohmann 2019

机译：八水合双4（44-二甲氧基-22-联吡啶）μ-（2R3R）-酒石（4-）双铜（II）的合成表征和晶体结构
7. Vanadium(V) Tartrato Complexes: Speciation in the H3O+(OH-)/H2VO4-/(2R,3R)-Tartrate System and X-ray Crystal Structures of Na4V4O8(rac-tart)212H2O and (NEt4)4V4O8((R,R)-tart)26H2O (tart = C4H2O64-) [O] . -1

机译：钒（v）Tartrato复合物：H3O +（OH - ）/ H2VO4 - /（2R，3R） - Na4 V4O8（RAC-TART）2 12H2O和（NET4）4的X射线晶体结构的形式V4O8（（R，R）-tart）2 6H2O（TART = C4H2O64-）

A new coordination mode for the tartrato ligand. Synthesis of vanadium(V) oxo peroxo tartrato complexes and the x-ray crystal structure of K-2[{VO(O-2)(L-tartH(2))}(2)(mu-H2O)].5H(2)O

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