First structural characterization of a zinc-bis(dialkylamide) compound: Zn{N[C(CH3)(2)(CH2)(3)C(CH3)(2)]}

Rees WS.; Schumann H.; Weimann R.; Just O.

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First structural characterization of a zinc-bis(dialkylamide) compound: Zn{N[C(CH3)(2)(CH2)(3)C(CH3)(2)]}

机译：锌双（二烷基酰胺）化合物的第一结构表征：Zn {N [C（CH3）（2）（CH2）（3）C（CH3）（2）]}

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The reaction of two molar equivalents of Li{N[C(CH3)(2)(CH2)(3)C(CH3)(2)]} with ZnCl2 in diethyl ether yields the title compound 1, which was characterized by H-1,C-13 and N-14 NMR, melting point, elemental analysis, mass spectrometry and single crystal X-ray diffraction. The structural characterization permits the first direct comparison of di(aryl)amide and di(triorganosilyl)amide examples with a di(alkyl)amide composition, thereby probing the nature of the Zn-N interaction. (C) 1998 Elsevier Science Ltd. All rights reserved. [References: 30]

机译：两摩尔当量的Li {N [C（CH3）（2）（CH2）（3）C（CH3）（2）]}与ZnCl2在乙醚中的反应生成标题化合物1，其特征在于H- 1，C-13和N-14 NMR，熔点，元素分析，质谱和单晶X射线衍射。结构表征允许将二（芳基）酰胺和二（三有机甲硅烷基）酰胺实例与二（烷基）酰胺组成进行首次直接比较，从而探究Zn-N相互作用的性质。（C）1998 Elsevier ScienceLtd。保留所有权利。 [参考：30]

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《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |1998年第6期|共4页
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Rees WS.; Schumann H.; Weimann R.; Just O.;
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中图分类化学;无机化学;
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1. First structural characterization of a zinc-bis(dialkylamide) compound: Zn{N[C(CH3)(2)(CH2)(3)C(CH3)(2)]} [J] . Rees WS., Schumann H., Weimann R., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 1998,第5a6期

机译：锌双（二烷基酰胺）化合物的第一结构表征：Zn {N [C（CH3）（2）（CH2）（3）C（CH3）（2）]}
2. Hydrothermal synthesis and structure of a zinc arsenate-oxalate, [NH3(CH2)(3)NH2(CH2)(3)NH3][Zn-3(AsO4)(HAsO4)(2)(C2O4)], and a zinc arsenate, [{NH3(CH3)(2)NH2(CH3)(3)NH3}(2)][Zn-6( AsO4)(4)-(HAsO4)(3)]center dot H2O, with three-dimensional structure [J] . Chakrabarti S., Natarajan S. Journal of the Chemical Society. Dalton Transactions . 2002,第22期

机译：草酸砷酸锌，[NH3（CH2）（3）NH2（CH2）（3）NH3] [Zn-3（AsO4）（HAsO4）（2）（C2O4）]和砷酸锌的水热合成和结构，[{NH3（CH3）（2）NH2（CH3）（3）NH3}（2）] [Zn-6（AsO4）（4）-（HAsO4）（3）]中心点H2O，具有三维结构
3. ORGANOMETALLIC SELENOLATES .5. SYNTHESIS AND COMPLEXING PROPERTIES OF 2-PROPENE- AND 2-METHYL-2-PROPENESELENOLATO MOLYBDENUM AND TUNGSTEN COMPOUNDS - CRYSTAL STRUCTURES OF CP(CO)(3)WSECH2C(CH3)=CH2, [CP(CO)(2)MOSECH2C(CH3)=CH2](2), [CP(CO)(3)MO(MU-SE [J] . Jones PG., Thone C., Laube J. Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 1997,第10期

机译：有机硒代.5。 CP（CO）（3）WSECH2C（CH3）= CH2，[CP（CO）（2）MOSECH2C（CH3）的2-丙烯-和2-甲基-2-丙炔硒基钼和钨化合物的合成和络合特性）= CH2]（2），[CP（CO）（3）MO（MU-SE）
4. Sol-gel Synthesis,Magnetic and Structural Characterization of BaFe_(11.6-2x)M_xTi_xO_19 (M=Co,Zn,Sn) Compounds [C] . G.Mendoza-Suarez, A.F.Fuentes, J.I.Escalante-Garcia, Materials Research Society Symposium . 2003

机译：溶胶 - 凝胶合成，磁性和结构表征Bafe_（11.6-2X）M_XTI_XO_19（M = CO，Zn，Sn）化合物
5. Progress Towards the Synthesis of a Novel 4-Carbon Linked ansa-Zirconcocene: [(CH2C(CH3)C(CH3)CH 2)(3-t-BuC5H3)2]ZrCl 2. [D] . Shamberg, Jonathan M. 2014

机译：新型4-碳连接的ansa-锆茂金属的合成进展：[（CH2C（CH3）C（CH3）CH 2）（3-t-BuC5H3）2] ZrCl 2。
6. In situ decarbonylation of NN-dimethylformamide to form dimethylammonium cations in the hybrid framework compound {(CH3)2NH22Zn{O3PC6H2(OH)2PO3}}n [O] . Josemaria S. Soriano, Bryan E. Galeas, Paul Garrett, 2019

机译：NN-二甲基酰胺在混合骨架化合物{（（CH3）2NH2 2 Zn {O3PC6H2（OH）2PO3}} n中原位脱甲磺酰化形成二甲基铵阳离子
7. Preparation and Characterization of Cobalt(III)-Dimethyldithiocarbamato Complexes Containing R2P(CH2)nPR2(R=CH3, C6H5;n=1,2,3,4) and PR3(R=C2H5, C6H5). Crystal Structure of Co{(CH3)2NCS2}{(CH3)2PCH2P(CH3)2}2(BF4)2 [O] . Masakazu Kita, Akiyoshi Okuyama, Kazuo Kashiwabara, 1990

机译：含有R2P（CH2）NPR2（R = CH3，C6H5; N = 1,2,3,4）和PR3（R = C2H5，C6H5）的含钴（III） - 二甲基二硫代氨基甲酰胺配合物的制备及表征。 Co {（CH3）2NCS2}晶体结构{（CH3）2PCH2P（CH3）2} 2（BF4）2
8. Metal Atom Synthesis of Metallaboron Clusters. 8. Synthesis of New Cobalt, Iron, and Nickel Clusters Derived from 2,6-C2B7H11. Structural Characterization of 2-ETA 6-C6(CH3)3H3 Fe-1,6-C2B7H9, 6-ETA 6-C6(CH3)3H3 Fe-9,10-C2B7H11, and 5,7,8-(CH3)-11,7,8,10- ETA 3-C4(CH3)4H niC3B7H7. [R] . Sneddon, L. G., Briguglio, J. J. 1986

机译：metallaboron团簇的金属原子合成。 8.衍生自2,6-C2B7H11的新的钴，铁和镍簇的合成。 2-ETa 6-C6（CH3）3H3Fe-1,6-C2B7H9,6-ETa6-C6（CH3）3H3Fe-9,10-C2B7H11和5,7,8-（CH3）的结构表征 - 11,7,8,10- ETa 3-C4（CH3）4HiC3B7H7。

First structural characterization of a zinc-bis(dialkylamide) compound: Zn{N[C(CH3)(2)(CH2)(3)C(CH3)(2)]}

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